DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Chemical preconcentrator

Abstract

A chemical preconcentrator is disclosed with applications to chemical sensing and analysis. The preconcentrator can be formed by depositing a resistive heating element (e.g. platinum) over a membrane (e.g. silicon nitride) suspended above a substrate. A coating of a sorptive material (e.g. a microporous hydrophobic sol-gel coating or a polymer coating) is formed on the suspended membrane proximate to the heating element to selective sorb one or more chemical species of interest over a time period, thereby concentrating the chemical species in the sorptive material. Upon heating the sorptive material with the resistive heating element, the sorbed chemical species are released for detection and analysis in a relatively high concentration and over a relatively short time period. The sorptive material can be made to selectively sorb particular chemical species of interest while not substantially sorbing other chemical species not of interest. The present invention has applications for use in forming high-sensitivity, rapid-response miniaturized chemical analysis systems (e.g. a "chem lab on a chip").

Inventors:
 [1];  [2]
  1. Albuquerque, NM
  2. Cedar Crest, NM
Issue Date:
Research Org.:
Sandia National Laboratories (SNL), Albuquerque, NM, and Livermore, CA (United States)
OSTI Identifier:
873483
Patent Number(s):
6171378
Assignee:
Sandia Corporation (Albuquerque, NM)
Patent Classifications (CPCs):
G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10S - TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
DOE Contract Number:  
AC04-94AL85000
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
chemical; preconcentrator; disclosed; applications; sensing; analysis; formed; depositing; resistive; heating; element; platinum; membrane; silicon; nitride; suspended; substrate; coating; sorptive; material; microporous; hydrophobic; sol-gel; polymer; proximate; selective; sorb; species; time; period; concentrating; sorbed; released; detection; relatively; concentration; selectively; particular; substantially; sorbing; forming; high-sensitivity; rapid-response; miniaturized; systems; chem; lab; chip; chemical sensing; resistive heating; polymer coating; sol-gel coating; chemical analysis; heating element; silicon nitride; time period; chemical species; chemical specie; sorptive material; selectively sorb; chemical preconcentrator; sorbed chemical; /96/55/

Citation Formats

Manginell, Ronald P, and Frye-Mason, Gregory C. Chemical preconcentrator. United States: N. p., 2001. Web.
Manginell, Ronald P, & Frye-Mason, Gregory C. Chemical preconcentrator. United States.
Manginell, Ronald P, and Frye-Mason, Gregory C. Mon . "Chemical preconcentrator". United States. https://www.osti.gov/servlets/purl/873483.
@article{osti_873483,
title = {Chemical preconcentrator},
author = {Manginell, Ronald P and Frye-Mason, Gregory C},
abstractNote = {A chemical preconcentrator is disclosed with applications to chemical sensing and analysis. The preconcentrator can be formed by depositing a resistive heating element (e.g. platinum) over a membrane (e.g. silicon nitride) suspended above a substrate. A coating of a sorptive material (e.g. a microporous hydrophobic sol-gel coating or a polymer coating) is formed on the suspended membrane proximate to the heating element to selective sorb one or more chemical species of interest over a time period, thereby concentrating the chemical species in the sorptive material. Upon heating the sorptive material with the resistive heating element, the sorbed chemical species are released for detection and analysis in a relatively high concentration and over a relatively short time period. The sorptive material can be made to selectively sorb particular chemical species of interest while not substantially sorbing other chemical species not of interest. The present invention has applications for use in forming high-sensitivity, rapid-response miniaturized chemical analysis systems (e.g. a "chem lab on a chip").},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Mon Jan 01 00:00:00 EST 2001},
month = {Mon Jan 01 00:00:00 EST 2001}
}

Works referenced in this record:

Microfabrication of membrane-based devices by HARSE and combined HARSE/wet etching
conference, August 1998


Micro gas-flow sensor with integrated heat sink and flow guide
journal, June 1996


Investigation of high-temperature degradation of platinum thin films with an in situ resistance measurement apparatus
journal, March 1998


Flexural plate wave resonator excited with Lorentz forces
journal, May 1998


Integrated smart two-dimensional thermal flow sensor with Seebeck-voltage-to-frequency conversion
journal, March 1992


Controlled microstructure oxide coatings for chemical sensors
conference, January 1990


Fabrication and properties of a Si-based high-sensitivity microcalorimetric gas sensor
journal, May 1995


Overview of micromachined platforms for thermal sensing and gas detection
conference, June 1997


Integrated Thermal Conductivity Vacuum Sensor
conference, June 1996


A sensitive Pirani vacuum sensor and the electrothermal SPICE modelling
journal, May 1996


A gas chromatographic air analyzer fabricated on a silicon wafer
journal, December 1979


Accumulation and trace measurements of phenothiazine drugs at DNA-modified electrodes
journal, October 1996


Template-Based Approaches to the Preparation of Amorphous, Nanoporous Silicas
journal, January 1996

  • Raman, Narayan K.; Anderson, Mark T.; Brinker, C. Jeffrey
  • Chemistry of Materials, Vol. 8, Issue 8, p. 1682-1701
  • URL: 10.1021/cm960138+

Microporous Silica Prepared by Organic Templating:  Relationship between the Molecular Template and Pore Structure
journal, May 1999


Microfabricated thermal absolute-pressure sensor with on-chip digital front-end processor
journal, January 1991


Micro-Hotplate gas Sensor
conference, June 1994


Microfabricated heavy metal ion sensor
journal, January 1995