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Title: Method and apparatus for selective removal of carbon monoxide

Abstract

There is provided a method and apparatus for treatment of a hydrogen-rich gas to reduce the carbon monoxide content thereof by reacting the carbon monoxide in the gas with an amount of oxygen sufficient to oxidize at least a portion of the carbon monoxide in the presence of a catalyst in a desired temperature range without substantial reaction of hydrogen. The catalyst is an iridium-based catalyst dispersed on, and supported on, a carrier. In the presence of the catalyst, carbon monoxide in a hydrogen-rich feed gas is selectively oxidized such that a product stream is produced with a very low carbon monoxide content.

Inventors:
 [1];  [2];  [3];  [4]
  1. East Rochester, NY
  2. Churchville, NY
  3. Pittsford, NY
  4. Bay City, MI
Issue Date:
Research Org.:
General Motors LLC, Detroit, MI (United States)
OSTI Identifier:
873451
Patent Number(s):
6162558
Assignee:
General Motors Corporation (Detroit, MI)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B - PERFORMING OPERATIONS B60 - VEHICLES IN GENERAL B60L - PROPULSION OF ELECTRICALLY-PROPELLED VEHICLES
DOE Contract Number:  
AC02-90CH10435
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
method; apparatus; selective; removal; carbon; monoxide; provided; treatment; hydrogen-rich; gas; reduce; content; reacting; amount; oxygen; sufficient; oxidize; portion; presence; catalyst; desired; temperature; range; substantial; reaction; hydrogen; iridium-based; dispersed; supported; carrier; feed; selectively; oxidized; product; stream; produced; monoxide content; product stream; temperature range; carbon monoxide; feed gas; selective removal; rich gas; desired temperature; hydrogen-rich gas; catalyst dispersed; rich feed; oxide content; based catalyst; /429/423/502/

Citation Formats

Borup, Rodney L, Skala, Glenn W, Brundage, Mark A, and LaBarge, William J. Method and apparatus for selective removal of carbon monoxide. United States: N. p., 2000. Web.
Borup, Rodney L, Skala, Glenn W, Brundage, Mark A, & LaBarge, William J. Method and apparatus for selective removal of carbon monoxide. United States.
Borup, Rodney L, Skala, Glenn W, Brundage, Mark A, and LaBarge, William J. Sat . "Method and apparatus for selective removal of carbon monoxide". United States. https://www.osti.gov/servlets/purl/873451.
@article{osti_873451,
title = {Method and apparatus for selective removal of carbon monoxide},
author = {Borup, Rodney L and Skala, Glenn W and Brundage, Mark A and LaBarge, William J},
abstractNote = {There is provided a method and apparatus for treatment of a hydrogen-rich gas to reduce the carbon monoxide content thereof by reacting the carbon monoxide in the gas with an amount of oxygen sufficient to oxidize at least a portion of the carbon monoxide in the presence of a catalyst in a desired temperature range without substantial reaction of hydrogen. The catalyst is an iridium-based catalyst dispersed on, and supported on, a carrier. In the presence of the catalyst, carbon monoxide in a hydrogen-rich feed gas is selectively oxidized such that a product stream is produced with a very low carbon monoxide content.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2000},
month = {1}
}