Palladium (II) catalyized polymerization of norbornene and acrylates
Abstract
Homopolymers or copolymers of acrylates, homopolymers or copolymers of norbornenes, and copolymers of acrylates with norbornenes, may be prepared by contacting acrylate and/or norbornene monomer reactant under polymerization conditions and in the presence of a solvent with a catalyst system consisting essentially of a Pd(II) dimer component having the formula: [(L)Pd(R)(X)].sub.2, where L is a monodentate phosphorus or nitrogen ligand, X is an anionic group, and R is an alkyl or aryl group.
- Inventors:
-
- State College, PA
- Annandale, NJ
- Exton, PA
- Issue Date:
- OSTI Identifier:
- 873203
- Patent Number(s):
- 6111041
- Application Number:
- 09/099,070
- Assignee:
- Penn State Research Foundation (University Park, PA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08F - MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- palladium; ii; catalyized; polymerization; norbornene; acrylates; homopolymers; copolymers; norbornenes; prepared; contacting; acrylate; monomer; reactant; conditions; presence; solvent; catalyst; consisting; essentially; pd; dimer; component; formula; monodentate; phosphorus; nitrogen; ligand; anionic; alkyl; aryl; consisting essentially; /526/
Citation Formats
Sen, Ayusman, Kacker, Smita, Hennis, April, and Polley, Jennifer D. Palladium (II) catalyized polymerization of norbornene and acrylates. United States: N. p., 2000.
Web.
Sen, Ayusman, Kacker, Smita, Hennis, April, & Polley, Jennifer D. Palladium (II) catalyized polymerization of norbornene and acrylates. United States.
Sen, Ayusman, Kacker, Smita, Hennis, April, and Polley, Jennifer D. Tue .
"Palladium (II) catalyized polymerization of norbornene and acrylates". United States. https://www.osti.gov/servlets/purl/873203.
@article{osti_873203,
title = {Palladium (II) catalyized polymerization of norbornene and acrylates},
author = {Sen, Ayusman and Kacker, Smita and Hennis, April and Polley, Jennifer D},
abstractNote = {Homopolymers or copolymers of acrylates, homopolymers or copolymers of norbornenes, and copolymers of acrylates with norbornenes, may be prepared by contacting acrylate and/or norbornene monomer reactant under polymerization conditions and in the presence of a solvent with a catalyst system consisting essentially of a Pd(II) dimer component having the formula: [(L)Pd(R)(X)].sub.2, where L is a monodentate phosphorus or nitrogen ligand, X is an anionic group, and R is an alkyl or aryl group.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2000},
month = {8}
}
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