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Title: Organo-Lewis acid as cocatalyst for cationic homogenous metallocene Ziegler-Natta olefin polymerizations

Abstract

The synthesis of the organo-Lewis acid perfluorobiphenylborane (PBB) and the activation of metallocenes for the formation of a variety of highly active homogeneous Ziegler-Natta metallocene olefin polymerization, copolymerization and ring-opening polymerization catalysts is described.

Inventors:
 [1];  [2]
  1. (Evanston, IL)
  2. (Chicago, IL)
Issue Date:
Research Org.:
Northwestern University
OSTI Identifier:
873089
Patent Number(s):
6087460
Assignee:
Northwestern University (Evanston, IL) CHO
DOE Contract Number:  
FG02-86ER13511
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
organo-lewis; acid; cocatalyst; cationic; homogenous; metallocene; ziegler-natta; olefin; polymerizations; synthesis; perfluorobiphenylborane; pbb; activation; metallocenes; formation; variety; highly; active; homogeneous; polymerization; copolymerization; ring-opening; catalysts; described; polymerization catalysts; olefin polymerization; lewis acid; polymerization catalyst; ring-opening polymerization; ziegler-natta olefin; olefin polymerizations; active homogeneous; organo-lewis acid; highly active; metallocene olefin; homogeneous ziegler-natta; olefin polymer; /526/999/

Citation Formats

Marks, Tobin J., and Chen, You-Xian. Organo-Lewis acid as cocatalyst for cationic homogenous metallocene Ziegler-Natta olefin polymerizations. United States: N. p., 2000. Web.
Marks, Tobin J., & Chen, You-Xian. Organo-Lewis acid as cocatalyst for cationic homogenous metallocene Ziegler-Natta olefin polymerizations. United States.
Marks, Tobin J., and Chen, You-Xian. Sat . "Organo-Lewis acid as cocatalyst for cationic homogenous metallocene Ziegler-Natta olefin polymerizations". United States. https://www.osti.gov/servlets/purl/873089.
@article{osti_873089,
title = {Organo-Lewis acid as cocatalyst for cationic homogenous metallocene Ziegler-Natta olefin polymerizations},
author = {Marks, Tobin J. and Chen, You-Xian},
abstractNote = {The synthesis of the organo-Lewis acid perfluorobiphenylborane (PBB) and the activation of metallocenes for the formation of a variety of highly active homogeneous Ziegler-Natta metallocene olefin polymerization, copolymerization and ring-opening polymerization catalysts is described.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2000},
month = {1}
}

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