Title: Modified lithium vanadium oxide electrode materials products and methods

Abstract

A method of improving certain vanadium oxide formulations is presented. The method concerns fluorine doping formulations having a nominal formula of LiV.sub.3 O.sub.8. Preferred average formulations are provided wherein the average oxidation state of the vanadium is at least 4.6. Herein preferred fluorine doped vanadium oxide materials, electrodes using such materials, and batteries including at least one electrode therein comprising such materials are provided.

Inventors:

Thackeray, Michael M ^[1]; Kahaian, Arthur J ^[2]; Visser, Donald R ^[1]; Dees, Dennis W ^[3]; Benedek, Roy ^[4]

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+ Show Inventor Affiliations

1. Naperville, IL
2. Chicago, IL
3. Downers Grove, IL
4. Western Springs, IL

Issue Date:

1999-01-01

Research Org.:

US ADVANCED BATTERY CONSORTIUM

OSTI Identifier:

872772

Patent Number(s):

6004697

Application Number:

08/985441

Assignee:

Minnesota Mining & Manufacturing Co. (St. Paul, MN); Hydro-Quebec Corporation (Montreal, CA)

Patent Classifications (CPCs):

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS

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C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F

C01G31/006 - {Compounds containing, besides vanadium, two or more other elements, with the exception of oxygen or hydrogen}
C01G39/006 - {Compounds containing, besides molybdenum, two or more other elements, with the exception of oxygen or hydrogen}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS

C01P2002/54 - one element only
C01P2002/72 - by d-values or two theta-values, e.g. as X-ray diagram
C01P2002/77 - by unit-cell parameters, atom positions or structure diagrams
C01P2006/40 - Electric properties

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

H01M4/1397 - of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M4/485 - of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M4/582 - {Halogenides}
H01M4/5825 - {Oxygenated metallic slats or polyanionic structures, e.g. borates, phosphates, silicates, olivines}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

Y02E60/10 - Energy storage

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DOE Contract Number:  

FC02-91CE50336

Resource Type:

Patent

Country of Publication:

United States

Language:

English

Subject:

modified; lithium; vanadium; oxide; electrode; materials; products; methods; method; improving; formulations; concerns; fluorine; doping; nominal; formula; liv; preferred; average; provided; oxidation; doped; electrodes; batteries; including; therein; comprising; oxide electrode; oxide materials; vanadium oxide; electrode material; oxide material; electrode materials; therein comprising; lithium vanadium; method concerns; oxide formulations; oxide form; electrode therein; /429/204/423/