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Title: Synthesis and use of (perfluoroaryl) fluoro-aluminate anion

Abstract

A trityl perfluorophenyl alumninate such as tris(2,2',2"-nonafluorobiphenyl) fluoroaluminate (PBA.sup.-) and its role as a cocatalyst in metallocene-mediated olefin polymerization is disclosed.

Inventors:
;
Issue Date:
Research Org.:
Northwestern Univ., Evanston, IL (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
872065
Patent Number(s):
5854166
Application Number:
08/912,617
Assignee:
Northwestern University (Evanston, IL)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
DOE Contract Number:  
FG02-86ER13511
Resource Type:
Patent
Resource Relation:
Patent File Date: 1997 Aug 18
Country of Publication:
United States
Language:
English
Subject:
synthesis; perfluoroaryl; fluoro-aluminate; anion; trityl; perfluorophenyl; alumninate; tris; -nonafluorobiphenyl; fluoroaluminate; pba; role; cocatalyst; metallocene-mediated; olefin; polymerization; disclosed; olefin polymerization; perfluorophenyl alumninate; metallocene-mediated olefin; trityl perfluorophenyl; fluoro-aluminate anion; olefin polymer; /502/526/999/

Citation Formats

Marks, Tobin J., and Chen, You-Xian. Synthesis and use of (perfluoroaryl) fluoro-aluminate anion. United States: N. p., 1998. Web.
Marks, Tobin J., & Chen, You-Xian. Synthesis and use of (perfluoroaryl) fluoro-aluminate anion. United States.
Marks, Tobin J., and Chen, You-Xian. Tue . "Synthesis and use of (perfluoroaryl) fluoro-aluminate anion". United States. https://www.osti.gov/servlets/purl/872065.
@article{osti_872065,
title = {Synthesis and use of (perfluoroaryl) fluoro-aluminate anion},
author = {Marks, Tobin J. and Chen, You-Xian},
abstractNote = {A trityl perfluorophenyl alumninate such as tris(2,2',2"-nonafluorobiphenyl) fluoroaluminate (PBA.sup.-) and its role as a cocatalyst in metallocene-mediated olefin polymerization is disclosed.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1998},
month = {12}
}

Works referenced in this record:

Reactive cationic dicyclopentadienyl zirconium(IV) complexes
journal, April 1986


Very Large Counteranion Modulation of Cationic Metallocene Polymerization Activity and Stereoregulation by a Sterically Congested (Perfluoroaryl)fluoroaluminate
journal, March 1997


Organo-Lewis Acids As Cocatalysts in Cationic Metallocene Polymerization Catalysis. Unusual Characteristics of Sterically Encumbered Tris(perfluorobiphenyl)borane
journal, January 1996