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Title: Fluorescent and cathodoluminescent phophors structurally related to sodalite

Abstract

Blue, quantum-confined phosphors for field-emission displays made by reducing metal (M) sulfoaluminates at high temperature. This yields phases of the type M.sub.4 (AlO.sub.2).sub.6 S. Bulk sulfide contaminant mixed with the reduced sulfoaluminate phase is removed by treating it with a chelating agent in nonaqueous solution. A photometric cathodoluminescence efficiency of 9 lumen/watt at 1000 V for Sr.sub.3 PbS(AlO.sub.2).sub.6 is observed. Undoped Sr.sub.4 S(AlO).sub.6 displays 5 lumen/watt at 1000 V, with excellent blue chromatic saturation.

Inventors:
 [1];  [2]
  1. Tijeras, NM
  2. San Diego, CA
Issue Date:
Research Org.:
Sandia National Laboratories (SNL), Albuquerque, NM, and Livermore, CA (United States)
OSTI Identifier:
871866
Patent Number(s):
5814245
Assignee:
Sandia Corporation (Albuquerque, NM)
Patent Classifications (CPCs):
C - CHEMISTRY C09 - DYES C09K - MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
DOE Contract Number:  
AC04-94AL85000
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
fluorescent; cathodoluminescent; phophors; structurally; related; sodalite; blue; quantum-confined; phosphors; field-emission; displays; reducing; metal; sulfoaluminates; temperature; yields; phases; type; bulk; sulfide; contaminant; mixed; reduced; sulfoaluminate; phase; removed; treating; chelating; agent; nonaqueous; solution; photometric; cathodoluminescence; efficiency; lumen; watt; 1000; sr; pbs; observed; undoped; excellent; chromatic; saturation; reducing metal; aqueous solution; chelating agent; nonaqueous solution; structurally related; emission displays; field-emission displays; emission display; /252/423/

Citation Formats

Phillips, Mark L. F., and Shea, Lauren E. Fluorescent and cathodoluminescent phophors structurally related to sodalite. United States: N. p., 1998. Web.
Phillips, Mark L. F., & Shea, Lauren E. Fluorescent and cathodoluminescent phophors structurally related to sodalite. United States.
Phillips, Mark L. F., and Shea, Lauren E. Thu . "Fluorescent and cathodoluminescent phophors structurally related to sodalite". United States. https://www.osti.gov/servlets/purl/871866.
@article{osti_871866,
title = {Fluorescent and cathodoluminescent phophors structurally related to sodalite},
author = {Phillips, Mark L. F. and Shea, Lauren E},
abstractNote = {Blue, quantum-confined phosphors for field-emission displays made by reducing metal (M) sulfoaluminates at high temperature. This yields phases of the type M.sub.4 (AlO.sub.2).sub.6 S. Bulk sulfide contaminant mixed with the reduced sulfoaluminate phase is removed by treating it with a chelating agent in nonaqueous solution. A photometric cathodoluminescence efficiency of 9 lumen/watt at 1000 V for Sr.sub.3 PbS(AlO.sub.2).sub.6 is observed. Undoped Sr.sub.4 S(AlO).sub.6 displays 5 lumen/watt at 1000 V, with excellent blue chromatic saturation.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1998},
month = {1}
}

Works referenced in this record:

Synthesis and structure of sulfide aluminate sodalites
journal, January 1992


Luminescence of Zn4X and Cd4X clusters (X = S, Se) in an aluminate or borate cage
journal, March 1995