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Title: Screening method for selecting semiconductor substrates having defects below a predetermined level in an oxide layer

Abstract

A method for screening or qualifying semiconductor substrates for integrated circuit fabrication. The method comprises the steps of annealing at least one semiconductor substrate at a first temperature in a defect-activating ambient (e.g. hydrogen, forming gas, or ammonia) for sufficient time for activating any defects within on oxide layer of the substrate; measuring a defect-revealing electrical characteristic of at least a portion of the oxide layer for determining a quantity of activated defects therein; and selecting substrates for which the quantity of activated defects is below a predetermined level. The defect-revealing electrical characteristic may be a capacitance-versus-voltage (C-V) characteristic or a current-versus-voltage (I-V) characteristic that is dependent on an electrical charge in the oxide layer generated by the activated defects. Embodiments of the present invention may be applied for screening any type of semiconductor substrate or wafer having an oxide layer formed thereon or therein. This includes silicon-on-insulator substrates formed by a separation by the implantation of oxygen (SIMOX) process or the bond and etch back silicon-on-insulator (BESOI) process, as well as silicon substrates having a thermal oxide layer or a deposited oxide layer.

Inventors:
 [1];  [1];  [1];  [1];  [1];  [1];  [2]
  1. Albuquerque, NM
  2. St. Martin le Vinoux, FR
Issue Date:
Research Org.:
Sandia National Laboratories (SNL), Albuquerque, NM, and Livermore, CA (United States)
OSTI Identifier:
871740
Patent Number(s):
5786231
Assignee:
Sandia Corporation (Albuquerque, NM)
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01L - SEMICONDUCTOR DEVICES
DOE Contract Number:  
AC04-94AL85000
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
screening; method; selecting; semiconductor; substrates; defects; below; predetermined; level; oxide; layer; qualifying; integrated; circuit; fabrication; comprises; steps; annealing; substrate; temperature; defect-activating; ambient; hydrogen; forming; gas; ammonia; sufficient; time; activating; measuring; defect-revealing; electrical; characteristic; portion; determining; quantity; activated; therein; capacitance-versus-voltage; c-v; current-versus-voltage; i-v; dependent; charge; generated; embodiments; applied; type; wafer; formed; thereon; silicon-on-insulator; separation; implantation; oxygen; simox; process; bond; etch; besoi; silicon; thermal; deposited; circuit fabrication; forming gas; electrical charge; silicon substrates; layer formed; semiconductor substrate; method comprises; silicon substrate; integrated circuit; oxide layer; sufficient time; predetermined level; formed thereon; semiconductor substrates; substrates formed; method comprise; insulator substrate; defects therein; electrical characteristic; /438/324/

Citation Formats

Warren, William L, Vanheusden, Karel J. R., Schwank, James R, Fleetwood, Daniel M, Shaneyfelt, Marty R, Winokur, Peter S, and Devine, Roderick A. B. Screening method for selecting semiconductor substrates having defects below a predetermined level in an oxide layer. United States: N. p., 1998. Web.
Warren, William L, Vanheusden, Karel J. R., Schwank, James R, Fleetwood, Daniel M, Shaneyfelt, Marty R, Winokur, Peter S, & Devine, Roderick A. B. Screening method for selecting semiconductor substrates having defects below a predetermined level in an oxide layer. United States.
Warren, William L, Vanheusden, Karel J. R., Schwank, James R, Fleetwood, Daniel M, Shaneyfelt, Marty R, Winokur, Peter S, and Devine, Roderick A. B. Tue . "Screening method for selecting semiconductor substrates having defects below a predetermined level in an oxide layer". United States. https://www.osti.gov/servlets/purl/871740.
@article{osti_871740,
title = {Screening method for selecting semiconductor substrates having defects below a predetermined level in an oxide layer},
author = {Warren, William L and Vanheusden, Karel J. R. and Schwank, James R and Fleetwood, Daniel M and Shaneyfelt, Marty R and Winokur, Peter S and Devine, Roderick A. B.},
abstractNote = {A method for screening or qualifying semiconductor substrates for integrated circuit fabrication. The method comprises the steps of annealing at least one semiconductor substrate at a first temperature in a defect-activating ambient (e.g. hydrogen, forming gas, or ammonia) for sufficient time for activating any defects within on oxide layer of the substrate; measuring a defect-revealing electrical characteristic of at least a portion of the oxide layer for determining a quantity of activated defects therein; and selecting substrates for which the quantity of activated defects is below a predetermined level. The defect-revealing electrical characteristic may be a capacitance-versus-voltage (C-V) characteristic or a current-versus-voltage (I-V) characteristic that is dependent on an electrical charge in the oxide layer generated by the activated defects. Embodiments of the present invention may be applied for screening any type of semiconductor substrate or wafer having an oxide layer formed thereon or therein. This includes silicon-on-insulator substrates formed by a separation by the implantation of oxygen (SIMOX) process or the bond and etch back silicon-on-insulator (BESOI) process, as well as silicon substrates having a thermal oxide layer or a deposited oxide layer.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jul 28 00:00:00 EDT 1998},
month = {Tue Jul 28 00:00:00 EDT 1998}
}

Works referenced in this record:

Oxygen gettering and oxide degradation during annealing of Si/SiO 2 /Si structures
journal, January 1995


Molecular hydrogen, E' center hole traps, and radiation induced interface traps in MOS devices
journal, January 1993


Combined electron spin resonance and capacitance‐voltage analysis of hydrogen‐annealing induced positive charge in buried SiO 2
journal, March 1995


Low dose SIMOX for ULSI applications
book, January 1995


Positive charging of buried SiO 2 by hydrogenation
journal, May 1994


SOI Materials
book, January 1991


Excess‐Si related defect centers in buried SiO 2 thin films
journal, June 1993


Characterization and depth profiling of E ’ defects in buried SiO 2
journal, July 1993


Ultraviolet radiation induced defect creation in buried SiO 2 layers
journal, October 1991