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Title: Alkane oxidation with porphyrins and metal complexes thereof having haloalkyl side chains

Abstract

Transition metal complexes of meso-haloalkylporphyrins, wherein the haloalkyl groups contain 2 to 8 carbon atoms have been found to be highly effective catalysts for oxidation of alkanes and for the decomposition of hydroperoxides.

Inventors:
 [1];  [2];  [3];  [4]
  1. (Glen Mills, PA)
  2. (Wallingford, PA)
  3. (Downingtown, PA)
  4. (Boothwyn, PA)
Issue Date:
Research Org.:
Sun Refining and Marketing Co., Marcus Hook, PA (United States)
OSTI Identifier:
871648
Patent Number(s):
5770728
Assignee:
Sun Company, Inc. (R&M) (Philadelphia, PA) NETL
DOE Contract Number:  
FC21-90MC26029
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
alkane; oxidation; porphyrins; metal; complexes; haloalkyl; chains; transition; meso-haloalkylporphyrins; contain; carbon; atoms; found; highly; effective; catalysts; alkanes; decomposition; hydroperoxides; alkane oxidation; metal complexes; carbon atoms; transition metal; highly effective; carbon atom; metal complex; effective catalysts; effective catalyst; /999/

Citation Formats

Wijesekera, Tilak, Lyons, James E., Ellis, Jr., Paul E., and Bhinde, Manoj V. Alkane oxidation with porphyrins and metal complexes thereof having haloalkyl side chains. United States: N. p., 1998. Web.
Wijesekera, Tilak, Lyons, James E., Ellis, Jr., Paul E., & Bhinde, Manoj V. Alkane oxidation with porphyrins and metal complexes thereof having haloalkyl side chains. United States.
Wijesekera, Tilak, Lyons, James E., Ellis, Jr., Paul E., and Bhinde, Manoj V. Thu . "Alkane oxidation with porphyrins and metal complexes thereof having haloalkyl side chains". United States. https://www.osti.gov/servlets/purl/871648.
@article{osti_871648,
title = {Alkane oxidation with porphyrins and metal complexes thereof having haloalkyl side chains},
author = {Wijesekera, Tilak and Lyons, James E. and Ellis, Jr., Paul E. and Bhinde, Manoj V.},
abstractNote = {Transition metal complexes of meso-haloalkylporphyrins, wherein the haloalkyl groups contain 2 to 8 carbon atoms have been found to be highly effective catalysts for oxidation of alkanes and for the decomposition of hydroperoxides.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1998},
month = {1}
}

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