Grafted methylenediphosphonate ion exchange resins
Abstract
An ion exchange resin is disclosed that is comprised of an insoluble copolymer onto which are grafted pendent groups that provide 1.0 to about 10 mmol/g dry weight phosphorous. The pendent groups have the formula ##STR1## wherein R is hydrogen, a cation or mixtures thereof; and R.sup.1 is hydrogen or an C.sub.1 -C.sub.2 alkyl group. The resin also contains zero to about 5 mmol/g dry weight of pendent aromatic sulfonate groups. Processes for making and using an ion exchange-resin are also disclosed.
- Inventors:
-
- Knoxville, TN
- Plymouth, PA
- Naperville, IL
- Issue Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- OSTI Identifier:
- 871348
- Patent Number(s):
- 5712347
- Application Number:
- 08/829998
- Assignee:
- ARCH Development Corp. (Chicago, IL); University of Tennessee Research Corp. (Knoxville, TN)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08F - MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- DOE Contract Number:
- W-31109-ENG-38
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- grafted; methylenediphosphonate; exchange; resins; resin; disclosed; comprised; insoluble; copolymer; pendent; provide; 10; mmol; dry; weight; phosphorous; formula; str1; hydrogen; cation; mixtures; -c; alkyl; contains; zero; aromatic; sulfonate; processes; exchange-resin; dry weight; exchange resin; exchange resins; weight phosphorous; grafted methylenediphosphonate; grafted pendent; insoluble copolymer; /525/521/
Citation Formats
Trochimcznk, Andrzej W, Gatrone, Ralph C, Alexandratos, Spiro, and Horwitz, E Philip. Grafted methylenediphosphonate ion exchange resins. United States: N. p., 1998.
Web.
Trochimcznk, Andrzej W, Gatrone, Ralph C, Alexandratos, Spiro, & Horwitz, E Philip. Grafted methylenediphosphonate ion exchange resins. United States.
Trochimcznk, Andrzej W, Gatrone, Ralph C, Alexandratos, Spiro, and Horwitz, E Philip. Tue .
"Grafted methylenediphosphonate ion exchange resins". United States. https://www.osti.gov/servlets/purl/871348.
@article{osti_871348,
title = {Grafted methylenediphosphonate ion exchange resins},
author = {Trochimcznk, Andrzej W and Gatrone, Ralph C and Alexandratos, Spiro and Horwitz, E Philip},
abstractNote = {An ion exchange resin is disclosed that is comprised of an insoluble copolymer onto which are grafted pendent groups that provide 1.0 to about 10 mmol/g dry weight phosphorous. The pendent groups have the formula ##STR1## wherein R is hydrogen, a cation or mixtures thereof; and R.sup.1 is hydrogen or an C.sub.1 -C.sub.2 alkyl group. The resin also contains zero to about 5 mmol/g dry weight of pendent aromatic sulfonate groups. Processes for making and using an ion exchange-resin are also disclosed.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 27 00:00:00 EST 1998},
month = {Tue Jan 27 00:00:00 EST 1998}
}
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Works referenced in this record:
Preparation of poly[ethylene-g-(vinylbenzyl chloride)] and functionalization with bis(phosphonic acid) derivatives
journal, May 1995
- Sundell, Mats J.; Ekman, Kenneth B.; Svarfvar, Bror L.
- Reactive Polymers, Vol. 25, Issue 1