Hydrogen-selective membrane
Abstract
A hydrogen-selective membrane comprises a tubular porous ceramic support having a palladium metal layer deposited on an inside surface of the ceramic support. The thickness of the palladium layer is greater than about 10 .mu.m but typically less than about 20 .mu.m. The hydrogen permeation rate of the membrane is greater than about 1.0 moles/m.sup.2. s at a temperature of greater than about 500.degree. C. and a transmembrane pressure difference of about 1,500 kPa. Moreover, the hydrogen-to-nitrogen selectivity is greater than about 600 at a temperature of greater than about 500.degree. C. and a transmembrane pressure of about 700 kPa. Hydrogen can be separated from a mixture of gases using the membrane. The method may include the step of heating the mixture of gases to a temperature of greater than about 400.degree. C. and less than about 1000.degree. C. before the step of flowing the mixture of gases past the membrane. The mixture of gases may include ammonia. The ammonia typically is decomposed to provide nitrogen and hydrogen using a catalyst such as nickel. The catalyst may be placed inside the tubular ceramic support. The mixture of gases may be supplied by an industrial process such as the mixture ofmore »
- Inventors:
-
- Boulder, CO
- Issue Date:
- Research Org.:
- SRI International, Menlo Park, CA (United States)
- OSTI Identifier:
- 871072
- Patent Number(s):
- 5652020
- Application Number:
- 08/593013
- Assignee:
- State of Oregon Acting By and Through State Board of Higher (Corvallis, OR)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
- DOE Contract Number:
- AC21-89MC26373
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- hydrogen-selective; membrane; comprises; tubular; porous; ceramic; support; palladium; metal; layer; deposited; inside; surface; thickness; 10; typically; 20; hydrogen; permeation; rate; moles; temperature; 500; degree; transmembrane; pressure; difference; kpa; moreover; hydrogen-to-nitrogen; selectivity; 600; 700; separated; mixture; gases; method; step; heating; 400; 1000; flowing; past; ammonia; decomposed; provide; nitrogen; catalyst; nickel; placed; supplied; industrial; process; exhaust; igcc; tubular ceramic; membrane comprises; hydrogen permeation; ceramic support; inside surface; exhaust gases; metal layer; layer deposited; industrial process; porous ceramic; exhaust gas; placed inside; pressure difference; tubular porous; permeation rate; hydrogen-selective membrane; palladium metal; palladium layer; nitrogen selectivity; selective membrane; /427/210/
Citation Formats
Collins, John P, and Way, J Douglas. Hydrogen-selective membrane. United States: N. p., 1997.
Web.
Collins, John P, & Way, J Douglas. Hydrogen-selective membrane. United States.
Collins, John P, and Way, J Douglas. Wed .
"Hydrogen-selective membrane". United States. https://www.osti.gov/servlets/purl/871072.
@article{osti_871072,
title = {Hydrogen-selective membrane},
author = {Collins, John P and Way, J Douglas},
abstractNote = {A hydrogen-selective membrane comprises a tubular porous ceramic support having a palladium metal layer deposited on an inside surface of the ceramic support. The thickness of the palladium layer is greater than about 10 .mu.m but typically less than about 20 .mu.m. The hydrogen permeation rate of the membrane is greater than about 1.0 moles/m.sup.2. s at a temperature of greater than about 500.degree. C. and a transmembrane pressure difference of about 1,500 kPa. Moreover, the hydrogen-to-nitrogen selectivity is greater than about 600 at a temperature of greater than about 500.degree. C. and a transmembrane pressure of about 700 kPa. Hydrogen can be separated from a mixture of gases using the membrane. The method may include the step of heating the mixture of gases to a temperature of greater than about 400.degree. C. and less than about 1000.degree. C. before the step of flowing the mixture of gases past the membrane. The mixture of gases may include ammonia. The ammonia typically is decomposed to provide nitrogen and hydrogen using a catalyst such as nickel. The catalyst may be placed inside the tubular ceramic support. The mixture of gases may be supplied by an industrial process such as the mixture of exhaust gases from the IGCC process.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Jan 01 00:00:00 EST 1997},
month = {Wed Jan 01 00:00:00 EST 1997}
}
Works referenced in this record:
A Palladium/Porous-Glass Composite Membrane for Hydrogen Separation
journal, October 1988
- Uemiya, Shigeyuki; Kude, Yukinori; Sugino, Kohzoh
- Chemistry Letters, Vol. 17, Issue 10