Halogenation of cobalt dicarbollide
Abstract
A method for selectively adding chlorine, bromine, or iodine to cobalt dicarbollide anions by means of electrophilic substitution reactions. Halogens are added only to the B10 and B10' positions of the anion. The process involves use of hypohalous acid or N-halosuccinimide or gaseous chlorine in the presence of iron.
- Inventors:
-
- Los Alamos, NM
- Issue Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- OSTI Identifier:
- 870958
- Patent Number(s):
- 5631390
- Assignee:
- Regents of University of California (Alameda, CA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- DOE Contract Number:
- W-7405-ENG-36
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- halogenation; cobalt; dicarbollide; method; selectively; adding; chlorine; bromine; iodine; anions; means; electrophilic; substitution; reactions; halogens; added; b10; positions; anion; process; involves; hypohalous; acid; n-halosuccinimide; gaseous; presence; iron; process involves; cobalt dicarbollide; substitution reactions; substitution reaction; /999/
Citation Formats
Hurlburt, Paul K, Abney, Kent D, and Kinkead, Scott A. Halogenation of cobalt dicarbollide. United States: N. p., 1997.
Web.
Hurlburt, Paul K, Abney, Kent D, & Kinkead, Scott A. Halogenation of cobalt dicarbollide. United States.
Hurlburt, Paul K, Abney, Kent D, and Kinkead, Scott A. Wed .
"Halogenation of cobalt dicarbollide". United States. https://www.osti.gov/servlets/purl/870958.
@article{osti_870958,
title = {Halogenation of cobalt dicarbollide},
author = {Hurlburt, Paul K and Abney, Kent D and Kinkead, Scott A},
abstractNote = {A method for selectively adding chlorine, bromine, or iodine to cobalt dicarbollide anions by means of electrophilic substitution reactions. Halogens are added only to the B10 and B10' positions of the anion. The process involves use of hypohalous acid or N-halosuccinimide or gaseous chlorine in the presence of iron.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1997},
month = {1}
}
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