Porphyrins and metal complexes thereof having haloalkyl side chains
Abstract
Transition metal complexes of meso-haloalkylporphyrins, wherein the haloalkyl groups contain 2 to 8 carbon atoms have been found to be highly effective catalysts for oxidation of alkanes and for the decomposition of hydroperoxides.
- Inventors:
-
- Glen Mills, PA
- Wallingford, PA
- (Downingtown, PA)
- Boothwyn, PA
- Issue Date:
- Research Org.:
- Sun Refining and Marketing Co., Marcus Hook, PA (United States)
- OSTI Identifier:
- 870850
- Patent Number(s):
- 5608054
- Assignee:
- Sun Company, Inc. (R&M) (Philadelphia, PA)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
- DOE Contract Number:
- FC21-90MC26029
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- porphyrins; metal; complexes; haloalkyl; chains; transition; meso-haloalkylporphyrins; contain; carbon; atoms; found; highly; effective; catalysts; oxidation; alkanes; decomposition; hydroperoxides; metal complexes; carbon atoms; transition metal; highly effective; carbon atom; metal complex; effective catalysts; effective catalyst; /999/
Citation Formats
Wijesekera, Tilak, Lyons, James E, Ellis, Jr., Paul E., and Bhinde, Manoj V. Porphyrins and metal complexes thereof having haloalkyl side chains. United States: N. p., 1997.
Web.
Wijesekera, Tilak, Lyons, James E, Ellis, Jr., Paul E., & Bhinde, Manoj V. Porphyrins and metal complexes thereof having haloalkyl side chains. United States.
Wijesekera, Tilak, Lyons, James E, Ellis, Jr., Paul E., and Bhinde, Manoj V. Wed .
"Porphyrins and metal complexes thereof having haloalkyl side chains". United States. https://www.osti.gov/servlets/purl/870850.
@article{osti_870850,
title = {Porphyrins and metal complexes thereof having haloalkyl side chains},
author = {Wijesekera, Tilak and Lyons, James E and Ellis, Jr., Paul E. and Bhinde, Manoj V},
abstractNote = {Transition metal complexes of meso-haloalkylporphyrins, wherein the haloalkyl groups contain 2 to 8 carbon atoms have been found to be highly effective catalysts for oxidation of alkanes and for the decomposition of hydroperoxides.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1997},
month = {1}
}
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Works referenced in this record:
Facile Synthesis of meso-Tetrakis(perfluoroalkyl)porphyrins: Spectroscopic Properties and X-ray Crystal Structure of Highly Electron-Deficient 5,10,15,20-Tetrakis(heptafluoropropyl)porphyrin
journal, November 1994
- DiMagno, Stephen G.; Williams, R. Allen; Therien, Michael J.
- The Journal of Organic Chemistry, Vol. 59, Issue 23