Process for recovering pertechnetate ions from an aqueous solution also containing other ions

Rogers, Robin; Horwitz, E Philip; Bond, Andrew H

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Title: Process for recovering pertechnetate ions from an aqueous solution also containing other ions

Abstract

A solid/liquid process for the separation and recovery of TcO.sub.4.sup.-1 ions from an aqueous solution is disclosed. The solid support comprises separation particles having surface-bonded poly(ethylene glycol) groups; whereas the aqueous solution from which the TcO.sub.4.sup.-1 ions are separated contains a poly(ethylene glycol) liquid/liquid biphase-forming amount of a dissolved salt. A solid/liquid phase admixture of separation particles containing bound TcO.sub.4.sup.-1 ions in such an aqueous solution that is free from MoO.sub.4.sup.-2 ions is also contemplated, as is a chromatography apparatus containing that solid/liquid phase admixture.

Inventors:

Rogers, Robin ^[1]; Horwitz, E Philip ^[2]; Bond, Andrew H ^[3]

DeKalb, IL
Naperville, IL
Tallahassee, FL

Issue Date:: 1997-01-01

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

OSTI Identifier:: 870837

Patent Number(s):: 5603834

Assignee:: Arch Development Corp. (Chicago, IL); Board of Regents for Northern Illinois University (DeKalb, IL)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D15/08 - Selective adsorption, e.g. chromatography

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J20/3204 - {Inorganic carriers, supports or substrates}
B01J20/321 - {consisting of a polymer obtained by reactions involving only carbon to carbon unsaturated bonds}
B01J20/3212 - {consisting of a polymer obtained by reactions otherwise than involving only carbon to carbon unsaturated bonds}
B01J20/3219 - {involving a particular spacer or linking group, e.g. for attaching an active group}
B01J20/3227 - {by end-capping, i.e. with or after the introduction of functional or ligand groups}
B01J20/3272 - {Polymers obtained by reactions otherwise than involving only carbon to carbon unsaturated bonds}
B01J20/3276 - {Copolymers}
B01J20/3278 - {Polymers being grafted on the carrier}

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DOE Contract Number:: W-31109-ENG-38

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: process; recovering; pertechnetate; aqueous; solution; containing; solid; liquid; separation; recovery; tco; -1; disclosed; support; comprises; particles; surface-bonded; poly; ethylene; glycol; separated; contains; biphase-forming; amount; dissolved; salt; phase; admixture; bound; free; moo; -2; contemplated; chromatography; apparatus; separation particles; ethylene glycol; solid support; particles containing; aqueous solution; liquid phase; separated contains; surface-bonded poly; comprises separation; support comprises; biphase-forming amount; liquid process; liquid biphase-forming; apparatus containing; dissolved salt; particles contain; /210/

Citation Formats


                    Rogers, Robin, Horwitz, E Philip, and Bond, Andrew H. Process for recovering pertechnetate ions from an aqueous solution also containing other ions.  United States: N. p., 1997. 
        Web.

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                    Rogers, Robin, Horwitz, E Philip, & Bond, Andrew H. Process for recovering pertechnetate ions from an aqueous solution also containing other ions.  United States.

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                    Rogers, Robin, Horwitz, E Philip, and Bond, Andrew H. Wed .  
        "Process for recovering pertechnetate ions from an aqueous solution also containing other ions".  United States.  https://www.osti.gov/servlets/purl/870837.

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@article{osti_870837,

  title        = {Process for recovering pertechnetate ions from an aqueous solution also containing other ions},

  author       = {Rogers, Robin and Horwitz, E Philip and Bond, Andrew H},

  abstractNote = {A solid/liquid process for the separation and recovery of TcO.sub.4.sup.-1 ions from an aqueous solution is disclosed. The solid support comprises separation particles having surface-bonded poly(ethylene glycol) groups; whereas the aqueous solution from which the TcO.sub.4.sup.-1 ions are separated contains a poly(ethylene glycol) liquid/liquid biphase-forming amount of a dissolved salt. A solid/liquid phase admixture of separation particles containing bound TcO.sub.4.sup.-1 ions in such an aqueous solution that is free from MoO.sub.4.sup.-2 ions is also contemplated, as is a chromatography apparatus containing that solid/liquid phase admixture.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {1997},

  month        = {1}

}

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Works referenced in this record:

Solid-phase cosolvents. Triphase catalytic hydrolysis of 1-bromoadamantane
journal, January 1979

Regen, Steven L.; Besse, Jacques J.; McLick, Jerome
Journal of the American Chemical Society, Vol. 101, Issue 1
https://doi.org/10.1021/ja00495a019

Surface affinity chromatographic separation of blood cells
journal, January 1983

Matsumoto, Ushiho; Shibusawa, Yōichi; Tanaka, Yō
Journal of Chromatography A, Vol. 268
https://doi.org/10.1016/S0021-9673(01)95436-6

Polystyrene-Immobilized PEG Chains
book, January 1992

Bayer, Ernst; Rapp, Wolfgang
Poly(Ethylene Glycol) Chemistry
https://doi.org/10.1007/978-1-4899-0703-5_20

Triphase Catalytic Saponification
journal, April 1983

Kimura, Yoshikazu; Reqen, Steven L.
Synthetic Communications, Vol. 13, Issue 6
https://doi.org/10.1080/00397918308081821

Thermodynamics of solvation of ions. Part 5.—Gibbs free energy of hydration at 298.15 K
journal, January 1991

Marcus, Yizhak
J. Chem. Soc., Faraday Trans., Vol. 87, Issue 18
https://doi.org/10.1039/FT9918702995

Non-supported and resin-supported oligo(oxyethylenes) as solid–liquid phase-transfer catalysts. Effect of chain length and head-group
journal, January 1981

Heffernan, James G.; MacKenzie, William M.; Sherrington, David C.
J. Chem. Soc., Perkin Trans. 2, Issue 3
https://doi.org/10.1039/P29810000514

Metal-ion complexation of noncyclic poly(oxyethylene) derivatives. 6. Solid-solid-liquid three phase transfer catalysis of polymer-bound acyclic poly(oxyethylene) derivatives. Applications to organic synthesis
journal, March 1979

Yanagida, Shozo; Takahashi, Kazutomo; Okahara, Mitsuo
The Journal of Organic Chemistry, Vol. 44, Issue 7
https://doi.org/10.1021/jo01321a015

Polyurethane foams as selective sorbents for noble metals
journal, January 1986

Jones, Lynn; Nel, Iris; Koch, Klaus R.
Analytica Chimica Acta, Vol. 182
https://doi.org/10.1016/S0003-2670(00)82437-X

Surface affinity chromatographic separation of blood cells
journal, January 1980

Matsumoto, Ushiho; Shibusawa, Yōichi
Journal of Chromatography A, Vol. 187, Issue 2
https://doi.org/10.1016/S0021-9673(00)80467-7

Polyether-based triphase catalysts. A synthetic comparison
journal, March 1981

Fukunishi, Koji; Czech, Bronislaw; Regen, Steven L.
The Journal of Organic Chemistry, Vol. 46, Issue 6
https://doi.org/10.1021/jo00319a039

Poly(ethylene glycols) and poly(ethylene glycol)-grafted copolymers are extraordinary catalysts for dehydrohalogenation under two-phase and three-phase conditions
journal, January 1983

Kimura, Yoshikazu; Regen, Steven L.
The Journal of Organic Chemistry, Vol. 48, Issue 2
https://doi.org/10.1021/jo00150a011

Surface affinity chromatographic separation of blood cells
journal, January 1984

Matsumoto, Ushiho; Ban, Midori; Shibusawa, Yōichi
Journal of Chromatography A, Vol. 285
https://doi.org/10.1016/S0021-9673(01)87736-0

Technetium Radiopharmaceuticals—Fundamentals, Synthesis, Structure, and Development
journal, December 1994

Schwochau, Klaus
Angewandte Chemie International Edition in English, Vol. 33, Issue 22
https://doi.org/10.1002/anie.199422581

Extraction mechanism of monovalent ion-pairs by polyurethane foams
journal, July 1992

Fong, P.
Talanta, Vol. 39, Issue 7
https://doi.org/10.1016/0039-9140(92)80103-K

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Similar Records

Title: Process for recovering pertechnetate ions from an aqueous solution also containing other ions

Abstract

Citation Formats

Solid-phase cosolvents. Triphase catalytic hydrolysis of 1-bromoadamantane journal, January 1979

Surface affinity chromatographic separation of blood cells journal, January 1983

Polystyrene-Immobilized PEG Chains book, January 1992

Triphase Catalytic Saponification journal, April 1983

Thermodynamics of solvation of ions. Part 5.—Gibbs free energy of hydration at 298.15 K journal, January 1991

Non-supported and resin-supported oligo(oxyethylenes) as solid–liquid phase-transfer catalysts. Effect of chain length and head-group journal, January 1981

Metal-ion complexation of noncyclic poly(oxyethylene) derivatives. 6. Solid-solid-liquid three phase transfer catalysis of polymer-bound acyclic poly(oxyethylene) derivatives. Applications to organic synthesis journal, March 1979

Polyurethane foams as selective sorbents for noble metals journal, January 1986

Surface affinity chromatographic separation of blood cells journal, January 1980

Polyether-based triphase catalysts. A synthetic comparison journal, March 1981

Poly(ethylene glycols) and poly(ethylene glycol)-grafted copolymers are extraordinary catalysts for dehydrohalogenation under two-phase and three-phase conditions journal, January 1983

Surface affinity chromatographic separation of blood cells journal, January 1984

Technetium Radiopharmaceuticals—Fundamentals, Synthesis, Structure, and Development journal, December 1994

Extraction mechanism of monovalent ion-pairs by polyurethane foams journal, July 1992

Solid-phase cosolvents. Triphase catalytic hydrolysis of 1-bromoadamantane
journal, January 1979

Surface affinity chromatographic separation of blood cells
journal, January 1983

Polystyrene-Immobilized PEG Chains
book, January 1992

Triphase Catalytic Saponification
journal, April 1983

Thermodynamics of solvation of ions. Part 5.—Gibbs free energy of hydration at 298.15 K
journal, January 1991

Non-supported and resin-supported oligo(oxyethylenes) as solid–liquid phase-transfer catalysts. Effect of chain length and head-group
journal, January 1981

Metal-ion complexation of noncyclic poly(oxyethylene) derivatives. 6. Solid-solid-liquid three phase transfer catalysis of polymer-bound acyclic poly(oxyethylene) derivatives. Applications to organic synthesis
journal, March 1979

Polyurethane foams as selective sorbents for noble metals
journal, January 1986

Surface affinity chromatographic separation of blood cells
journal, January 1980

Polyether-based triphase catalysts. A synthetic comparison
journal, March 1981

Poly(ethylene glycols) and poly(ethylene glycol)-grafted copolymers are extraordinary catalysts for dehydrohalogenation under two-phase and three-phase conditions
journal, January 1983

Surface affinity chromatographic separation of blood cells
journal, January 1984

Technetium Radiopharmaceuticals—Fundamentals, Synthesis, Structure, and Development
journal, December 1994

Extraction mechanism of monovalent ion-pairs by polyurethane foams
journal, July 1992