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Title: Substituted dipyrromethanes and their preparation

Abstract

New chemical compounds, bis(pyrrol-2-yl)halocarbylmethanes, also known as meso-halocarbyl dipyrromethanes, are made by recting pyrrole in either of two reaction schemes. Once such scheme converts pyrrole through an intermediate, a halocarbyl carbonyl pyrrole, to a [2-(1-hydroxyl-1-hydro-1-halocarbyl)pyrrole], and then converts the latter to the desired halocarbyldipyrromethane; the last step in this scheme is a novel and useful method in itself. The other such sequence converts pyrrole, by reaction with a halocarbyl aldehyde, directly to the desired halocarbyl dipyrromethane.

Inventors:
 [1]
  1. Glen Mills, PA
Issue Date:
Research Org.:
Sun Refining and Marketing Co., Marcus Hook, PA (United States)
OSTI Identifier:
870813
Patent Number(s):
5599948
Assignee:
Sun Company, Inc. (Philadelphia, PA)
DOE Contract Number:  
FC21-90MC26029
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
substituted; dipyrromethanes; preparation; chemical; compounds; bis; pyrrol-2-yl; halocarbylmethanes; meso-halocarbyl; recting; pyrrole; reaction; schemes; scheme; converts; intermediate; halocarbyl; carbonyl; 2-; 1-hydroxyl-1-hydro-1-halocarbyl; latter; desired; halocarbyldipyrromethane; step; novel; useful; method; sequence; aldehyde; directly; dipyrromethane; converts pyrrole; useful method; chemical compounds; reaction scheme; reaction schemes; substituted dipyrromethanes; recting pyrrole; sequence converts; scheme converts; carbonyl pyrrole; meso-halocarbyl dipyrromethanes; halocarbyl dipyrromethane; chemical compound; halocarbyl carbonyl; halocarbyl aldehyde; desired halocarbyldipyrromethane; desired halocarbyl; /999/

Citation Formats

Wijesekera, Tilak. Substituted dipyrromethanes and their preparation. United States: N. p., 1997. Web.
Wijesekera, Tilak. Substituted dipyrromethanes and their preparation. United States.
Wijesekera, Tilak. Wed . "Substituted dipyrromethanes and their preparation". United States. https://www.osti.gov/servlets/purl/870813.
@article{osti_870813,
title = {Substituted dipyrromethanes and their preparation},
author = {Wijesekera, Tilak},
abstractNote = {New chemical compounds, bis(pyrrol-2-yl)halocarbylmethanes, also known as meso-halocarbyl dipyrromethanes, are made by recting pyrrole in either of two reaction schemes. Once such scheme converts pyrrole through an intermediate, a halocarbyl carbonyl pyrrole, to a [2-(1-hydroxyl-1-hydro-1-halocarbyl)pyrrole], and then converts the latter to the desired halocarbyldipyrromethane; the last step in this scheme is a novel and useful method in itself. The other such sequence converts pyrrole, by reaction with a halocarbyl aldehyde, directly to the desired halocarbyl dipyrromethane.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1997},
month = {1}
}

Patent:

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