Cesium titanium silicate and method of making
Abstract
The invention is the new material, a ternary compound of cesium, silica, and titania, together with a method of making the ternary compound, cesium titanium silicate pollucite. More specifically, the invention is Cs.sub.2 Ti.sub.2 Si.sub.4 O.sub.13 pollucite which is a new crystalline phase representing a novel class of Ti-containing zeolites. Compositions contain relatively high Cs.sub.2 O and TiO.sub.2 loadings and are durable glass and ceramic materials. The amount of TiO.sub.2 and Cs.sub.2 that can be incorporated into these glasses and crystalline ceramics far exceeds the limits set for the borosilicate high level waste glass.
- Inventors:
-
- West Richland, WA
- Issue Date:
- Research Org.:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- OSTI Identifier:
- 870768
- Patent Number(s):
- 5591420
- Assignee:
- Battelle Memorial Institute (Richland, WA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10S - TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- DOE Contract Number:
- AC06-76RL01830
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- cesium; titanium; silicate; method; material; ternary; compound; silica; titania; pollucite; specifically; cs; 13; crystalline; phase; representing; novel; ti-containing; zeolites; compositions; contain; relatively; loadings; durable; glass; ceramic; materials; amount; incorporated; glasses; ceramics; exceeds; limits; set; borosilicate; level; waste; ceramic material; ceramic materials; crystalline phase; waste glass; level waste; ternary compound; compositions contain; cesium titanium; titanium silicate; ceramic mater; /423/501/588/
Citation Formats
Balmer, Mari L. Cesium titanium silicate and method of making. United States: N. p., 1997.
Web.
Balmer, Mari L. Cesium titanium silicate and method of making. United States.
Balmer, Mari L. Wed .
"Cesium titanium silicate and method of making". United States. https://www.osti.gov/servlets/purl/870768.
@article{osti_870768,
title = {Cesium titanium silicate and method of making},
author = {Balmer, Mari L},
abstractNote = {The invention is the new material, a ternary compound of cesium, silica, and titania, together with a method of making the ternary compound, cesium titanium silicate pollucite. More specifically, the invention is Cs.sub.2 Ti.sub.2 Si.sub.4 O.sub.13 pollucite which is a new crystalline phase representing a novel class of Ti-containing zeolites. Compositions contain relatively high Cs.sub.2 O and TiO.sub.2 loadings and are durable glass and ceramic materials. The amount of TiO.sub.2 and Cs.sub.2 that can be incorporated into these glasses and crystalline ceramics far exceeds the limits set for the borosilicate high level waste glass.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1997},
month = {1}
}
Works referenced in this record:
Immobilization of Cesium into Pollucite Structure by Hydrothermal Hot-Pressing
journal, January 1987
- Yanagisawa, Kazumichi; Nishioka, Mamoru; Yamasaki, Nakamichi
- Journal of Nuclear Science and Technology, Vol. 24, Issue 1
Fundamental Study on the Solidification of Cs + and Sr 2+ with Hydrous Ti IV Oxide Modified with Si and Zr
journal, January 1992
- Inoue, Y.; Yamazaki, H.; Erza, R.
- MRS Proceedings, Vol. 294