Copper-containing zeolite catalysts
Abstract
A catalyst useful in the conversion of nitrogen oxides or in the synthesis of nitriles or imines from amines, formed by preparing an intimate mechanical mixture of a copper (II)-containing species, such as CuO or CuCl.sub.2, or elemental copper, with a zeolite having a pore mouth comprising 10 oxygen atoms, such as ZSM-5, converting the elemental copper or copper (II) to copper (I), and driving the copper (I) into the zeolite.
- Inventors:
-
- Baton Rouge, LA
- Sofia, BG
- Issue Date:
- Research Org.:
- Louisiana State Univ., Baton Rouge, LA
- OSTI Identifier:
- 870729
- Patent Number(s):
- 5583081
- Assignee:
- Board of Supervisors of Louisiana State University and Agricultural and (Baton Rouge, LA); Bulgarian Academy of Sciences (Sofia, BG)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
- DOE Contract Number:
- FG05-92ER14291
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- copper-containing; zeolite; catalysts; catalyst; useful; conversion; nitrogen; oxides; synthesis; nitriles; imines; amines; formed; preparing; intimate; mechanical; mixture; copper; ii; -containing; species; cuo; cucl; elemental; pore; mouth; comprising; 10; oxygen; atoms; zsm-5; converting; driving; catalyst useful; nitrogen oxide; nitrogen oxides; oxygen atoms; zeolite catalyst; containing species; mechanical mixture; oxygen atom; zeolite catalysts; /502/999/
Citation Formats
Price, Geoffrey L, and Kanazirev, Vladislav. Copper-containing zeolite catalysts. United States: N. p., 1996.
Web.
Price, Geoffrey L, & Kanazirev, Vladislav. Copper-containing zeolite catalysts. United States.
Price, Geoffrey L, and Kanazirev, Vladislav. Mon .
"Copper-containing zeolite catalysts". United States. https://www.osti.gov/servlets/purl/870729.
@article{osti_870729,
title = {Copper-containing zeolite catalysts},
author = {Price, Geoffrey L and Kanazirev, Vladislav},
abstractNote = {A catalyst useful in the conversion of nitrogen oxides or in the synthesis of nitriles or imines from amines, formed by preparing an intimate mechanical mixture of a copper (II)-containing species, such as CuO or CuCl.sub.2, or elemental copper, with a zeolite having a pore mouth comprising 10 oxygen atoms, such as ZSM-5, converting the elemental copper or copper (II) to copper (I), and driving the copper (I) into the zeolite.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Mon Jan 01 00:00:00 EST 1996},
month = {Mon Jan 01 00:00:00 EST 1996}
}
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Works referenced in this record:
Adsorption-desorption Properties of Nitrogen Monoxide on Metal Ion-exchanged Zeolites
journal, May 1992
- Zhang, Wenxiang; Yahiro, Hidenori; Mizuno, Noritaka
- Chemistry Letters, Vol. 21, Issue 5
Temperature-programmed desorption of nitric oxide over Cu-ZSM-5
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- Li, Yuejin; Armor, John N.
- Applied Catalysis, Vol. 76, Issue 2
Adsorption Studies on Cu-ZSM-5: Characterization of the Unique Properties of Ion-Exchanged Cu
journal, August 1993
- Parrillo, D. J.; Dolenec, D.; Gorte, R. J.
- Journal of Catalysis, Vol. 142, Issue 2
Introduction of Cations into Zeolites by Solid-State Reaction
book, January 1991
- Karge, Hellmut G.; Beyer, Hermann K.
- Studies in Surface Science and Catalysis
High-temperature interaction of solid Cu chlorides and Cu oxides in mixtures with H-forms of ZSM-5 and Y zeolites
journal, January 1992
- Karge, Hellmut G.; Wichterlová, Blanka; Beyer, Hermann K.
- J. Chem. Soc., Faraday Trans., Vol. 88, Issue 9