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Title: Inorganic-organic composite polymers and methods of making

Abstract

The invention is a composition of an inorganic-organic polymer composite and a method of making it. The inorganic portion of the fundamental polymer composite polymer repeat is a speciated inorganic heterocyclic compound, and the organic portion of the polymer repeat is a cyclic organic radical anion compound having at least two charged sites. The composition of the present invention is made by combining a cyclic organic radical anion compound with a speciated inorganic heterocyclic compound by a nucleophilic substitution thereby forming a polymer of an inorganic-organic composite. The cyclic organic radical anion compound is preferably generated electrochemically. The nucleophilic substitution is alternately carried out chemically or electrochemically. A preferred embodiment of the present invention includes performing the nucleophilic substitution at the cathode of an electrochemical cell.

Inventors:
 [1];  [1]
  1. Richland, WA
Issue Date:
Research Org.:
Pacific Northwest National Laboratory (PNNL), Richland, WA
OSTI Identifier:
870666
Patent Number(s):
5569736
Assignee:
Battelle Memorial Institute (Richland, WA)
DOE Contract Number:  
AC06-76RL01830
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
inorganic-organic; composite; polymers; methods; composition; polymer; method; inorganic; portion; fundamental; repeat; speciated; heterocyclic; compound; organic; cyclic; radical; anion; charged; sites; combining; nucleophilic; substitution; forming; preferably; generated; electrochemically; alternately; carried; chemically; preferred; embodiment; performing; cathode; electrochemical; cell; electrochemical cell; preferred embodiment; organic polymer; polymer composite; nucleophilic substitution; composite polymer; organic portion; cyclic organic; preferably generated; charged sites; /528/205/

Citation Formats

Josowicz, Mira A, and Exarhos, Gregory J. Inorganic-organic composite polymers and methods of making. United States: N. p., 1996. Web.
Josowicz, Mira A, & Exarhos, Gregory J. Inorganic-organic composite polymers and methods of making. United States.
Josowicz, Mira A, and Exarhos, Gregory J. Mon . "Inorganic-organic composite polymers and methods of making". United States. https://www.osti.gov/servlets/purl/870666.
@article{osti_870666,
title = {Inorganic-organic composite polymers and methods of making},
author = {Josowicz, Mira A and Exarhos, Gregory J},
abstractNote = {The invention is a composition of an inorganic-organic polymer composite and a method of making it. The inorganic portion of the fundamental polymer composite polymer repeat is a speciated inorganic heterocyclic compound, and the organic portion of the polymer repeat is a cyclic organic radical anion compound having at least two charged sites. The composition of the present invention is made by combining a cyclic organic radical anion compound with a speciated inorganic heterocyclic compound by a nucleophilic substitution thereby forming a polymer of an inorganic-organic composite. The cyclic organic radical anion compound is preferably generated electrochemically. The nucleophilic substitution is alternately carried out chemically or electrochemically. A preferred embodiment of the present invention includes performing the nucleophilic substitution at the cathode of an electrochemical cell.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1996},
month = {1}
}

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