Inorganic-organic composite polymers and methods of making
Abstract
The invention is a composition of an inorganic-organic polymer composite and a method of making it. The inorganic portion of the fundamental polymer composite polymer repeat is a speciated inorganic heterocyclic compound, and the organic portion of the polymer repeat is a cyclic organic radical anion compound having at least two charged sites. The composition of the present invention is made by combining a cyclic organic radical anion compound with a speciated inorganic heterocyclic compound by a nucleophilic substitution thereby forming a polymer of an inorganic-organic composite. The cyclic organic radical anion compound is preferably generated electrochemically. The nucleophilic substitution is alternately carried out chemically or electrochemically. A preferred embodiment of the present invention includes performing the nucleophilic substitution at the cathode of an electrochemical cell.
- Inventors:
-
- Richland, WA
- Issue Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- OSTI Identifier:
- 870666
- Patent Number(s):
- 5569736
- Assignee:
- Battelle Memorial Institute (Richland, WA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- DOE Contract Number:
- AC06-76RL01830
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- inorganic-organic; composite; polymers; methods; composition; polymer; method; inorganic; portion; fundamental; repeat; speciated; heterocyclic; compound; organic; cyclic; radical; anion; charged; sites; combining; nucleophilic; substitution; forming; preferably; generated; electrochemically; alternately; carried; chemically; preferred; embodiment; performing; cathode; electrochemical; cell; electrochemical cell; preferred embodiment; organic polymer; polymer composite; nucleophilic substitution; composite polymer; organic portion; cyclic organic; preferably generated; charged sites; /528/205/
Citation Formats
Josowicz, Mira A, and Exarhos, Gregory J. Inorganic-organic composite polymers and methods of making. United States: N. p., 1996.
Web.
Josowicz, Mira A, & Exarhos, Gregory J. Inorganic-organic composite polymers and methods of making. United States.
Josowicz, Mira A, and Exarhos, Gregory J. Mon .
"Inorganic-organic composite polymers and methods of making". United States. https://www.osti.gov/servlets/purl/870666.
@article{osti_870666,
title = {Inorganic-organic composite polymers and methods of making},
author = {Josowicz, Mira A and Exarhos, Gregory J},
abstractNote = {The invention is a composition of an inorganic-organic polymer composite and a method of making it. The inorganic portion of the fundamental polymer composite polymer repeat is a speciated inorganic heterocyclic compound, and the organic portion of the polymer repeat is a cyclic organic radical anion compound having at least two charged sites. The composition of the present invention is made by combining a cyclic organic radical anion compound with a speciated inorganic heterocyclic compound by a nucleophilic substitution thereby forming a polymer of an inorganic-organic composite. The cyclic organic radical anion compound is preferably generated electrochemically. The nucleophilic substitution is alternately carried out chemically or electrochemically. A preferred embodiment of the present invention includes performing the nucleophilic substitution at the cathode of an electrochemical cell.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1996},
month = {1}
}
Works referenced in this record:
Phosphonitrilic Chemistry
journal, April 1968
- Allcock, Harry R.
- Chemical & Engineering News Archive, Vol. 46, Issue 18