Propenyl ether monomers for photopolymerization
Abstract
Propenyl ether monomers of formula V wherein n is an integer from one to six and A is selected from cyclic ethers, polyether and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of formula V together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.
- Inventors:
- Issue Date:
- Research Org.:
- Rensselaer Polytechnic Inst., Troy, NY (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 870651
- Patent Number(s):
- 5567858
- Application Number:
- 08/571,200
- Assignee:
- Rensselaer Polytechnic Institute (Troy, NY)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08F - MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- DOE Contract Number:
- FG02-91ER12117
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 1995 Dec 12
- Country of Publication:
- United States
- Language:
- English
- Subject:
- /999/522/
Citation Formats
Crivello, James V. Propenyl ether monomers for photopolymerization. United States: N. p., 1996.
Web.
Crivello, James V. Propenyl ether monomers for photopolymerization. United States.
Crivello, James V. Mon .
"Propenyl ether monomers for photopolymerization". United States. https://www.osti.gov/servlets/purl/870651.
@article{osti_870651,
title = {Propenyl ether monomers for photopolymerization},
author = {Crivello, James V.},
abstractNote = {Propenyl ether monomers of formula V wherein n is an integer from one to six and A is selected from cyclic ethers, polyether and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of formula V together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1996},
month = {1}
}
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Works referenced in this record:
Structure and reactivity of α,β-unsaturated ethers. III. Cationic copolymerizations of alkenyl alkyl ethers
journal, April 1968
- Okuyama, T.; Fueno, T.; Furukawa, J.
- Journal of Polymer Science Part A-1: Polymer Chemistry, Vol. 6, Issue 4
Synthesis, characterization, and properties of novel aromatic bispropenyl ethers
journal, September 1984
- Crivello, James V.; Conlon, David A.
- Journal of Polymer Science: Polymer Chemistry Edition, Vol. 22, Issue 9
Structure and reactivity of α,β-unsaturated ethers. XIII. Cationic copolymerization and acid-catalyzed hydrolysis of 1,2-dialkoxyethylenes
journal, March 1971
- Okuyama, Tadashi; Fueno, Takayuki
- Journal of Polymer Science Part A-1: Polymer Chemistry, Vol. 9, Issue 3
Cationic polymerization of α,β-disubstituted olefins. Part II. Cationic polymerization of propenyl N-butyl ether
journal, July 1967
- Mizote, A.; Kusudo, S.; Higashimura, T.
- Journal of Polymer Science Part A-1: Polymer Chemistry, Vol. 5, Issue 7
Structure and reactivity of α,β-unsaturated ethers. VII. Electronic effects of the β-methyl substitution on the cationic polymerizabilities of alkyl vinyl ethers
journal, November 1969
- Fueno, T.; Okuyama, T.; Furukawa, J.
- Journal of Polymer Science Part A-1: Polymer Chemistry, Vol. 7, Issue 11
New synthesis of aryl-substituted sulfonium salts and their applications in photoinitiated cationic polymerization
journal, November 1990
- Akhtar, S. R.; Crivello, J. V.; Lee, J. L.
- Chemistry of Materials, Vol. 2, Issue 6
Structure and reactivity α,β-unsaturated ethers. II. Cationic copolymerizations of propenyl isobutyl ether
journal, April 1968
- Okuyama, T.; Fueno, T.; Furukawa, J.
- Journal of Polymer Science Part A-1: Polymer Chemistry, Vol. 6, Issue 4