Substantially isotactic, linear, alternating copolymers of carbon monoxide and an olefin
Abstract
The compound, [Pd(Me-DUPHOS)(MeCN).sub.2 ](BF.sub.4).sub.2, [Me-DUPHOS: 1,2-bis(2,5-dimethylphospholano)benzene] is an effective catalyst for the highly enantioselective, alternating copolymerization of olefins, such as aliphatic .alpha.-olefins, with carbon monoxide to form optically active, isotactic polymers which can serve as excellent starting materials for the synthesis of other classes of chiral polymers. For example, the complete reduction of a propylene-carbon monoxide copolymer resulted in the formation of a novel, optically active poly(1,4-alcohol). Also, the previously described catalyst is a catalyst for the novel alternating isomerization cooligomerization of 2-butene with carbon monoxide to form optically active, isotactic poly(1,5-ketone)
- Inventors:
- Issue Date:
- Research Org.:
- Pennsylvania State Univ., University Park, PA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 870434
- Patent Number(s):
- 5521281
- Application Number:
- 08/424,777
- Assignee:
- The Penn State Research Foundation (University Park, PA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- DOE Contract Number:
- FG02-84ER13295
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 1995 Apr 18
- Country of Publication:
- United States
- Language:
- English
- Subject:
- /528/525/
Citation Formats
Sen, Ayusman, and Jiang, Zhaozhong. Substantially isotactic, linear, alternating copolymers of carbon monoxide and an olefin. United States: N. p., 1996.
Web.
Sen, Ayusman, & Jiang, Zhaozhong. Substantially isotactic, linear, alternating copolymers of carbon monoxide and an olefin. United States.
Sen, Ayusman, and Jiang, Zhaozhong. Mon .
"Substantially isotactic, linear, alternating copolymers of carbon monoxide and an olefin". United States. https://www.osti.gov/servlets/purl/870434.
@article{osti_870434,
title = {Substantially isotactic, linear, alternating copolymers of carbon monoxide and an olefin},
author = {Sen, Ayusman and Jiang, Zhaozhong},
abstractNote = {The compound, [Pd(Me-DUPHOS)(MeCN).sub.2 ](BF.sub.4).sub.2, [Me-DUPHOS: 1,2-bis(2,5-dimethylphospholano)benzene] is an effective catalyst for the highly enantioselective, alternating copolymerization of olefins, such as aliphatic .alpha.-olefins, with carbon monoxide to form optically active, isotactic polymers which can serve as excellent starting materials for the synthesis of other classes of chiral polymers. For example, the complete reduction of a propylene-carbon monoxide copolymer resulted in the formation of a novel, optically active poly(1,4-alcohol). Also, the previously described catalyst is a catalyst for the novel alternating isomerization cooligomerization of 2-butene with carbon monoxide to form optically active, isotactic poly(1,5-ketone)},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Mon Jan 01 00:00:00 EST 1996},
month = {Mon Jan 01 00:00:00 EST 1996}
}
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Works referenced in this record:
Efficient palladium catalysts for the copolymerization of carbon monoxide with olefins to produce perfectly alternating polyketones
journal, October 1991
- Drent, E.; Van Broekhoven, J. A. M.; Doyle, M. J.
- Journal of Organometallic Chemistry, Vol. 417, Issue 1-2
Preparation and use of C2-symmetric bis(phospholanes): production of .alpha.-amino acid derivatives via highly enantioselective hydrogenation reactions
journal, November 1993
- Burk, Mark J.; Feaster, John E.; Nugent, William A.
- Journal of the American Chemical Society, Vol. 115, Issue 22
Regioselectivity Control in the Palladium-Catalyzed Copolymerization of Propylene with Carbon Monoxide
journal, March 1992
- Batistini, Antonio; Consiglio, Giambattista; Suter, Ulrich W.
- Angewandte Chemie International Edition in English, Vol. 31, Issue 3
Mechanistic aspects of metal-catalyzed alternating copolymerization of olefins with carbon monoxide
journal, June 1993
- Sen, Ayusman
- Accounts of Chemical Research, Vol. 26, Issue 6
The search for larger and more weakly coordinating anions
journal, May 1993
- Strauss, Steven H.
- Chemical Reviews, Vol. 93, Issue 3
Stereochemistry of alternating copolymers of vinyl olefins with carbon monoxide
journal, June 1992
- Barsacchi, Marco; Batistini, Antonio; Consiglio, Giambattista
- Macromolecules, Vol. 25, Issue 13
Regio‐ and stereo‐selective alternating copolymerization of carbon monoxide with propene
journal, September 1993
- Xu, Frank Y.; Zhao, Allen X.; Chien, James C. W.
- Die Makromolekulare Chemie, Vol. 194, Issue 9, p. 2579-2603
Palladium(II) catalysts for living alternating copolymerization of olefins and carbon monoxide
journal, July 1992
- Brookhart, M.; Rix, Francis C.; DeSimone, J. M.
- Journal of the American Chemical Society, Vol. 114, Issue 14