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Title: Processes for producing low cost, high efficiency silicon solar cells

Abstract

Processes which utilize rapid thermal processing (RTP) are provided for inexpensively producing high efficiency silicon solar cells. The RTP processes preserve minority carrier bulk lifetime .tau. and permit selective adjustment of the depth of the diffused regions, including emitter and back surface field (bsf), within the silicon substrate. Silicon solar cell efficiencies of 16.9% have been achieved. In a first RTP process, an RTP step is utilized to simultaneously diffuse phosphorus and aluminum into the front and back surfaces, respectively, of a silicon substrate. Moreover, an in situ controlled cooling procedure preserves the carrier bulk lifetime .tau. and permits selective adjustment of the depth of the diffused regions. In a second RTP process, both simultaneous diffusion of the phosphorus and aluminum as well as annealing of the front and back contacts are accomplished during the RTP step. In a third RTP process, the RTP step accomplishes simultaneous diffusion of the phosphorus and aluminum, annealing of the contacts, and annealing of a double-layer antireflection/passivation coating SiN/SiO.sub.x.

Inventors:
 [1];  [2];  [3]
  1. Marietta, GA
  2. Duluth, GA
  3. Atlanta, GA
Issue Date:
OSTI Identifier:
870383
Patent Number(s):
5510271
Assignee:
Georgia Tech Research Corporation (Atlanta, GA)
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01L - SEMICONDUCTOR DEVICES
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
E21-H21; E21-H31
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
processes; producing; cost; efficiency; silicon; solar; cells; utilize; rapid; thermal; processing; rtp; provided; inexpensively; preserve; minority; carrier; bulk; lifetime; tau; permit; selective; adjustment; depth; diffused; regions; including; emitter; surface; field; bsf; substrate; cell; efficiencies; 16; achieved; process; step; utilized; simultaneously; diffuse; phosphorus; aluminum; front; surfaces; respectively; moreover; situ; controlled; cooling; procedure; preserves; permits; simultaneous; diffusion; annealing; contacts; accomplished; third; accomplishes; double-layer; antireflection; passivation; coating; sio; solar cell; solar cells; silicon substrate; silicon solar; minority carrier; rtp process; rapid thermal; thermal processing; permits selective; passivation coating; cooling procedure; efficiency silicon; carrier bulk; rtp processes; controlled cooling; utilize rapid; surface field; inexpensively producing; preserve minority; processes preserve; /438/136/

Citation Formats

Rohatgi, Ajeet, Chen, Zhizhang, and Doshi, Parag. Processes for producing low cost, high efficiency silicon solar cells. United States: N. p., 1996. Web.
Rohatgi, Ajeet, Chen, Zhizhang, & Doshi, Parag. Processes for producing low cost, high efficiency silicon solar cells. United States.
Rohatgi, Ajeet, Chen, Zhizhang, and Doshi, Parag. Mon . "Processes for producing low cost, high efficiency silicon solar cells". United States. https://www.osti.gov/servlets/purl/870383.
@article{osti_870383,
title = {Processes for producing low cost, high efficiency silicon solar cells},
author = {Rohatgi, Ajeet and Chen, Zhizhang and Doshi, Parag},
abstractNote = {Processes which utilize rapid thermal processing (RTP) are provided for inexpensively producing high efficiency silicon solar cells. The RTP processes preserve minority carrier bulk lifetime .tau. and permit selective adjustment of the depth of the diffused regions, including emitter and back surface field (bsf), within the silicon substrate. Silicon solar cell efficiencies of 16.9% have been achieved. In a first RTP process, an RTP step is utilized to simultaneously diffuse phosphorus and aluminum into the front and back surfaces, respectively, of a silicon substrate. Moreover, an in situ controlled cooling procedure preserves the carrier bulk lifetime .tau. and permits selective adjustment of the depth of the diffused regions. In a second RTP process, both simultaneous diffusion of the phosphorus and aluminum as well as annealing of the front and back contacts are accomplished during the RTP step. In a third RTP process, the RTP step accomplishes simultaneous diffusion of the phosphorus and aluminum, annealing of the contacts, and annealing of a double-layer antireflection/passivation coating SiN/SiO.sub.x.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1996},
month = {1}
}

Works referenced in this record:

Multicrystalline silicon solar cells processed by rapid thermal processing
conference, January 1993


Simultaneous Junction Formation Using a Directed Energy Light Source
journal, October 1986


A novel and effective PECVD SiO/sub 2//SiN antireflection coating for Si solar cells
journal, June 1993


Rapid optical thermal processing of silicon solar cells
conference, January 1993