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Title: Process for making propenyl ethers and photopolymerizable compositions containing them

Abstract

Propenyl ether monomers of formula V wherein n is an integer from one to six and A is selected from cyclic ethers, polyether and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of formula V together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.

Inventors:
Issue Date:
Research Org.:
Rensselaer Polytechnic Inst., Troy, NY (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
870264
Patent Number(s):
5486545
Application Number:
08/232,507
Assignee:
Rensselaer Polytechnic Institute (Troy, NY)
Patent Classifications (CPCs):
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08F - MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
DOE Contract Number:  
FG02-91ER12117
Resource Type:
Patent
Resource Relation:
Patent File Date: 1994 Apr 25
Country of Publication:
United States
Language:
English
Subject:
/522/999/

Citation Formats

Crivello, James V. Process for making propenyl ethers and photopolymerizable compositions containing them. United States: N. p., 1996. Web.
Crivello, James V. Process for making propenyl ethers and photopolymerizable compositions containing them. United States.
Crivello, James V. Mon . "Process for making propenyl ethers and photopolymerizable compositions containing them". United States. https://www.osti.gov/servlets/purl/870264.
@article{osti_870264,
title = {Process for making propenyl ethers and photopolymerizable compositions containing them},
author = {Crivello, James V.},
abstractNote = {Propenyl ether monomers of formula V wherein n is an integer from one to six and A is selected from cyclic ethers, polyether and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of formula V together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1996},
month = {1}
}

Works referenced in this record:

Structure and reactivity of α,β-unsaturated ethers. III. Cationic copolymerizations of alkenyl alkyl ethers
journal, April 1968


Synthesis, characterization, and properties of novel aromatic bispropenyl ethers
journal, September 1984


Structure and reactivity of α,β-unsaturated ethers. XIII. Cationic copolymerization and acid-catalyzed hydrolysis of 1,2-dialkoxyethylenes
journal, March 1971


Cationic polymerization of α,β-disubstituted olefins. Part II. Cationic polymerization of propenyl N-butyl ether
journal, July 1967


New synthesis of aryl-substituted sulfonium salts and their applications in photoinitiated cationic polymerization
journal, November 1990


Structure and reactivity α,β-unsaturated ethers. II. Cationic copolymerizations of propenyl isobutyl ether
journal, April 1968