Metal complexes of substituted Gable porphyrins as oxidation catalysts
Abstract
Transition metal complexes of Gable porphyrins having two porphyrin rings connected through a linking group, and having on the porphyrin rings electron-withdrawing groups, such as halogen, nitro or cyano. These complexes are useful as catalysts for the oxidation of organic compounds, e.g. alkanes.
- Inventors:
-
- Wallingford, PA
- (Downingtown, PA)
- Murrysville, PA
- Issue Date:
- Research Org.:
- Sun Refining and Marketing Co., Marcus Hook, PA (United States)
- OSTI Identifier:
- 870233
- Patent Number(s):
- 5480986
- Assignee:
- Sun Company, Inc. (R&M) (Philadelphia, PA)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- DOE Contract Number:
- FC21-90MC26029
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- metal; complexes; substituted; gable; porphyrins; oxidation; catalysts; transition; porphyrin; rings; connected; linking; electron-withdrawing; halogen; nitro; cyano; useful; organic; compounds; alkanes; oxidation catalysts; metal complexes; organic compound; organic compounds; transition metal; oxidation catalyst; metal complex; gable porphyrins; porphyrin rings; /999/
Citation Formats
Lyons, James E, Ellis, Jr., Paul E., and Wagner, Richard W. Metal complexes of substituted Gable porphyrins as oxidation catalysts. United States: N. p., 1996.
Web.
Lyons, James E, Ellis, Jr., Paul E., & Wagner, Richard W. Metal complexes of substituted Gable porphyrins as oxidation catalysts. United States.
Lyons, James E, Ellis, Jr., Paul E., and Wagner, Richard W. Mon .
"Metal complexes of substituted Gable porphyrins as oxidation catalysts". United States. https://www.osti.gov/servlets/purl/870233.
@article{osti_870233,
title = {Metal complexes of substituted Gable porphyrins as oxidation catalysts},
author = {Lyons, James E and Ellis, Jr., Paul E. and Wagner, Richard W},
abstractNote = {Transition metal complexes of Gable porphyrins having two porphyrin rings connected through a linking group, and having on the porphyrin rings electron-withdrawing groups, such as halogen, nitro or cyano. These complexes are useful as catalysts for the oxidation of organic compounds, e.g. alkanes.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1996},
month = {1}
}
Works referenced in this record:
Cooperative dioxygen binding by cobalt(II) gable porphyrin in homogeneous solution
journal, May 1983
- Tabushi, Iwao; Sasaki, Tomikazu
- Journal of the American Chemical Society, Vol. 105, Issue 9
Synthesis and chromophoric interactions of an ‘ortho-gable-porphyrin.’ a novel tetraphenylporphyrin dimer
journal, January 1989
- Meier, Heinrich; Kobuke, Yoshiaki; Kugimiya, Shin-ichi
- J. Chem. Soc., Chem. Commun., Vol. 0, Issue 14
Gable-porphyrin as a cytochrome-c3 model
journal, January 1982
- Tabushi, Iwao; Sasaki, Tomikazu
- Tetrahedron Letters, Vol. 23, Issue 18