Conversion of fullerenes to diamonds

Gruen, Dieter M

Title: Conversion of fullerenes to diamonds

Abstract

A method of forming synthetic diamond or diamond-like films on a substrate surface. The method involves the steps of providing a vapor selected from the group of fullerene molecules or an inert gas/fullerene molecule mixture, providing energy to the fullerene molecules consisting of carbon-carbon bonds, the energized fullerene molecules breaking down to form fragments of fullerene molecules including C.sub.2 molecules and depositing the energized fullerene molecules with C.sub.2 fragments onto the substrate with farther fragmentation occurring and forming a thickness of diamond or diamond-like films on the substrate surface.

Inventors:

Gruen, Dieter M ^[1]

1324 59th St., Downers Grove, IL 60515

Issue Date:: 1995-01-01

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

OSTI Identifier:: 870136

Patent Number(s):: 5462776

Assignee:: Gruen, Dieter M. (1324 59th St., Downers Grove, IL 60515)

Patent Classifications (CPCs):: C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL

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C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B32/26 - Preparation

C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL
C23C14/0605 - {Carbon}
C23C14/0611 - {Diamond}
C23C14/221 - {Ion beam deposition
C23C16/27 - Diamond only
C23C16/274 - {using microwave discharges}
C23C16/277 - {using other elements in the gas phase besides carbon and hydrogen

C - CHEMISTRY C30 - CRYSTAL GROWTH C30B - SINGLE-CRYSTAL-GROWTH
C30B23/02 - Epitaxial-layer growth
C30B25/105 - {by irradiation or electric discharge}
C30B29/04 - Diamond
C30B33/00 - After-treatment of single crystals or homogeneous polycrystalline material with defined structure

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01J - ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
H01J9/025 - {of field emission cathodes}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10S - TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10S423/39 - Fullerene, e.g. c60, c70 derivative and related process
Y10S427/102 - Fullerene type base or coating
Y10S427/106 - Utilizing plasma, e.g. corona, glow discharge, cold plasma

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T428/30 - Self-sustaining carbon mass or layer with impregnant or other layer

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Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: conversion; fullerenes; diamonds; method; forming; synthetic; diamond; diamond-like; films; substrate; surface; involves; steps; providing; vapor; selected; fullerene; molecules; inert; gas; molecule; mixture; energy; consisting; carbon-carbon; bonds; energized; breaking; form; fragments; including; depositing; farther; fragmentation; occurring; thickness; forming synthetic; synthetic diamond; method involves; inert gas; substrate surface; fullerene molecules; carbon bond; molecules including; providing energy; method involve; /427/117/423/428/

Citation Formats


                    Gruen, Dieter M. Conversion of fullerenes to diamonds.  United States: N. p., 1995. 
        Web.

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                    Gruen, Dieter M. Conversion of fullerenes to diamonds.  United States.

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                    Gruen, Dieter M. Sun .  
        "Conversion of fullerenes to diamonds".  United States.  https://www.osti.gov/servlets/purl/870136.

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@article{osti_870136,

  title        = {Conversion of fullerenes to diamonds},

  author       = {Gruen, Dieter M},

  abstractNote = {A method of forming synthetic diamond or diamond-like films on a substrate surface. The method involves the steps of providing a vapor selected from the group of fullerene molecules or an inert gas/fullerene molecule mixture, providing energy to the fullerene molecules consisting of carbon-carbon bonds, the energized fullerene molecules breaking down to form fragments of fullerene molecules including C.sub.2 molecules and depositing the energized fullerene molecules with C.sub.2 fragments onto the substrate with farther fragmentation occurring and forming a thickness of diamond or diamond-like films on the substrate surface.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {1995},

  month        = {1}

}

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Works referenced in this record:

High-yield synthesis, separation, and mass-spectrometric characterization of fullerenes C60 to C266
journal, September 1991

Parker, Deborah Holmes; Wurz, Peter; Chatterjee, Kuntal
Journal of the American Chemical Society, Vol. 113, Issue 20
https://doi.org/10.1021/ja00020a008

Laser deposition of carbon clusters on surfaces: A new approach to the study of Fullerenes
journal, December 1990

Meijer, Gerard; Bethune, Donald S.
The Journal of Chemical Physics, Vol. 93, Issue 11
https://doi.org/10.1063/1.459360

Delayed electron emission from photoexcited C ₆₀
journal, November 1991

Wurz, Peter; Lykke, Keith R.
The Journal of Chemical Physics, Vol. 95, Issue 9
https://doi.org/10.1063/1.461046

Resilience of all-carbon molecules C60, C70, and C84: a surface-scattering time-of-flight investigation
journal, October 1991

Beck, Rainer D.; St. John, Pamela; Alvarez, Marcos M.
The Journal of Physical Chemistry, Vol. 95, Issue 21
https://doi.org/10.1021/j100174a066

Solid C60: a new form of carbon
journal, September 1990

Krätschmer, W.; Lamb, Lowell D.; Fostiropoulos, K.
Nature, Vol. 347, Issue 6291
https://doi.org/10.1038/347354a0

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Title: Conversion of fullerenes to diamonds

Abstract

Citation Formats

High-yield synthesis, separation, and mass-spectrometric characterization of fullerenes C60 to C266 journal, September 1991

Laser deposition of carbon clusters on surfaces: A new approach to the study of Fullerenes journal, December 1990

Delayed electron emission from photoexcited C 60 journal, November 1991

Resilience of all-carbon molecules C60, C70, and C84: a surface-scattering time-of-flight investigation journal, October 1991

Solid C60: a new form of carbon journal, September 1990

High-yield synthesis, separation, and mass-spectrometric characterization of fullerenes C60 to C266
journal, September 1991

Laser deposition of carbon clusters on surfaces: A new approach to the study of Fullerenes
journal, December 1990

Delayed electron emission from photoexcited C ₆₀
journal, November 1991

Resilience of all-carbon molecules C60, C70, and C84: a surface-scattering time-of-flight investigation
journal, October 1991

Solid C60: a new form of carbon
journal, September 1990