Sterically shielded diboron-containing metallocene olefin polymerization catalysts

Title: Sterically shielded diboron-containing metallocene olefin polymerization catalysts

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Abstract

A non-coordinating anion, preferably containing a sterically shielded diboron hydride, if combined with a cyclopenta-dienyl-substituted metallocene cation component, such as a zirconocene metallocene, is a useful olefin polymerization catalyst component. The anion preferably has the formula ##STR1## where R is branched lower alkyl, such as t-butyl.

Inventors:: Marks, Tobin J.; Ja, Li; Yang, Xinmin

Issue Date:: 1995-09-05

Research Org.:: Northwestern Univ., Evanston, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 870055

Patent Number(s):: 5447895

Application Number:: 08/209,668

Assignee:: Northwestern University (Evanston, IL)

Patent Classifications (CPCs):: C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08F - MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

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C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08F - MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C08F4/619 - Component covered by group C08F4/60 containing a transition metal-carbon bond {

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J31/146 - {of boron}

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08F - MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C08F10/00 - Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J2531/48 - Zirconium
B01J31/2295 - {Cyclic compounds, e.g. cyclopentadienyls}

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08F - MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C08F4/54 - together with other compounds thereof
C08F4/61908 - {in combination with an ionising compound other than alumoxane, e.g.

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DOE Contract Number:: FG02-86ER13511

Resource Type:: Patent

Resource Relation:: Patent File Date: 1994 Mar 10

Country of Publication:: United States

Language:: English

Subject:: sterically; shielded; diboron-containing; metallocene; olefin; polymerization; catalysts; non-coordinating; anion; preferably; containing; diboron; hydride; combined; cyclopenta-dienyl-substituted; cation; component; zirconocene; useful; catalyst; formula; str1; branched; alkyl; t-butyl; boron hydride; preferably contain; polymerization catalysts; olefin polymerization; containing metal; polymerization catalyst; catalyst component; preferably containing; metallocene olefin; sterically shielded; shielded diboron; non-coordinating anion; olefin polymer; cation component; coordinating anion; /502/526/

Citation Formats


                    Marks, Tobin J., Ja, Li, and Yang, Xinmin. Sterically shielded diboron-containing metallocene olefin polymerization catalysts.  United States: N. p., 1995. 
        Web.

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                    Marks, Tobin J., Ja, Li, & Yang, Xinmin. Sterically shielded diboron-containing metallocene olefin polymerization catalysts.  United States.

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                    Marks, Tobin J., Ja, Li, and Yang, Xinmin. Tue .  
        "Sterically shielded diboron-containing metallocene olefin polymerization catalysts".  United States.  https://www.osti.gov/servlets/purl/870055.

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@article{osti_870055,

  title        = {Sterically shielded diboron-containing metallocene olefin polymerization catalysts},

  author       = {Marks, Tobin J. and Ja, Li and Yang, Xinmin},

  abstractNote = {A non-coordinating anion, preferably containing a sterically shielded diboron hydride, if combined with a cyclopenta-dienyl-substituted metallocene cation component, such as a zirconocene metallocene, is a useful olefin polymerization catalyst component. The anion preferably has the formula ##STR1## where R is branched lower alkyl, such as t-butyl.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {1995},

  month        = {9}

}

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