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Title: Isolation of levoglucosan from lignocellulosic pyrolysis oil derived from wood or waste newsprint

Abstract

A method is provided for preparing high purity levoglucosan from lignocellulosic pyrolysis oils derived from wood or waste newsprint. The method includes reducing wood or newsprint to fine particle sizes, treating the particles with a hot mineral acid for a predetermined period of time, and filtering off and drying resulting solid wood or newsprint material; pyrolyzing the dried solid wood or newsprint material at temperatures between about 350.degree. and 375.degree. C. to produce pyrolysis oils; treating the oils to liquid-liquid extraction with methyl isobutyl ketone to remove heavy tar materials from the oils, and to provide an aqueous fraction mixture of the oils containing primarily levoglucosan; treating the aqueous fraction mixtures with a basic metal salt in an amount sufficient to elevate pH values to a range of about 12 to about 12.5 and adding an amount of the salt in excess of the amount needed to obtain the pH range to remove colored materials of impurities from the oil and form a slurry, and freeze-drying the resulting slurry to produce a dry solid residue; and extracting the levoglucosan from the residue using ethyl acetate solvent to produce a purified crystalline levoglucosan.

Inventors:
 [1]
  1. (Lakewood, CO)
Issue Date:
Research Org.:
MIDWEST RESEARCH INSTITUTE
Sponsoring Org.:
USDOE
OSTI Identifier:
869974
Patent Number(s):
5432276
Assignee:
Midwest Research Institute (Kansas City, MO) CHO
DOE Contract Number:  
AC02-83CH10093
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
isolation; levoglucosan; lignocellulosic; pyrolysis; oil; derived; wood; waste; newsprint; method; provided; preparing; purity; oils; reducing; fine; particle; sizes; treating; particles; hot; mineral; acid; predetermined; period; time; filtering; drying; resulting; solid; material; pyrolyzing; dried; temperatures; 350; degree; 375; produce; liquid-liquid; extraction; methyl; isobutyl; ketone; remove; heavy; tar; materials; provide; aqueous; fraction; mixture; containing; primarily; mixtures; basic; metal; salt; amount; sufficient; elevate; ph; values; range; 12; adding; excess; obtain; colored; impurities; form; slurry; freeze-drying; dry; residue; extracting; ethyl; acetate; solvent; purified; crystalline; mineral acid; ph range; pyrolysis oils; dry solid; pyrolysis oil; particle size; metal salt; amount sufficient; solid residue; ph value; ethyl acetate; predetermined period; particle sizes; ph values; remove heavy; basic metal; isobutyl ketone; oils containing; oil derived; methyl isobutyl; resulting slurry; resulting solid; fine particle; liquid extract; purity levoglucosan; waste newsprint; liquid extraction; aqueous fraction; lignocellulosic pyrolysis; liquid-liquid extraction; /999/

Citation Formats

Moens, Luc. Isolation of levoglucosan from lignocellulosic pyrolysis oil derived from wood or waste newsprint. United States: N. p., 1995. Web.
Moens, Luc. Isolation of levoglucosan from lignocellulosic pyrolysis oil derived from wood or waste newsprint. United States.
Moens, Luc. Sun . "Isolation of levoglucosan from lignocellulosic pyrolysis oil derived from wood or waste newsprint". United States. https://www.osti.gov/servlets/purl/869974.
@article{osti_869974,
title = {Isolation of levoglucosan from lignocellulosic pyrolysis oil derived from wood or waste newsprint},
author = {Moens, Luc},
abstractNote = {A method is provided for preparing high purity levoglucosan from lignocellulosic pyrolysis oils derived from wood or waste newsprint. The method includes reducing wood or newsprint to fine particle sizes, treating the particles with a hot mineral acid for a predetermined period of time, and filtering off and drying resulting solid wood or newsprint material; pyrolyzing the dried solid wood or newsprint material at temperatures between about 350.degree. and 375.degree. C. to produce pyrolysis oils; treating the oils to liquid-liquid extraction with methyl isobutyl ketone to remove heavy tar materials from the oils, and to provide an aqueous fraction mixture of the oils containing primarily levoglucosan; treating the aqueous fraction mixtures with a basic metal salt in an amount sufficient to elevate pH values to a range of about 12 to about 12.5 and adding an amount of the salt in excess of the amount needed to obtain the pH range to remove colored materials of impurities from the oil and form a slurry, and freeze-drying the resulting slurry to produce a dry solid residue; and extracting the levoglucosan from the residue using ethyl acetate solvent to produce a purified crystalline levoglucosan.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1995},
month = {1}
}

Patent:

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