Method and apparatus for producing oxygenates from hydrocarbons
Abstract
A chemical reactor for oxygenating hydrocarbons includes: a) a dielectric barrier discharge plasma cell, the plasma cell comprising a pair of electrodes having a dielectric material and void therebetween, the plasma cell comprising a hydrocarbon gas inlet feeding to the void; b) a solid oxide electrochemical cell, the electrochemical cell comprising a solid oxide electrolyte positioned between a porous cathode and a porous anode, an oxygen containing gas inlet stream feeding to the porous cathode side of the electrochemical cell; c) a first gas passageway feeding from the void to the anode side of the electrochemical cell; and d) a gas outlet feeding from the anode side of the electrochemical cell to expel reaction products from the chemical reactor. A method of oxygenating hydrocarbons is also disclosed.
- Inventors:
-
- Idaho Falls, ID
- Issue Date:
- Research Org.:
- Idaho National Laboratory (INL), Idaho Falls, ID (United States)
- OSTI Identifier:
- 869947
- Patent Number(s):
- 5427747
- Assignee:
- Lockheed Idaho Technologies Company (Idaho Falls, ID)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
- DOE Contract Number:
- AC07-76ID01570
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- method; apparatus; producing; oxygenates; hydrocarbons; chemical; reactor; oxygenating; dielectric; barrier; discharge; plasma; cell; comprising; pair; electrodes; material; void; therebetween; hydrocarbon; gas; inlet; feeding; solid; oxide; electrochemical; electrolyte; positioned; porous; cathode; anode; oxygen; containing; stream; passageway; outlet; expel; reaction; products; disclosed; chemical reactor; dielectric barrier; plasma cell; oxygen containing; oxide electrochemical; gas outlet; hydrocarbon gas; gas inlet; electrochemical cell; solid oxide; reaction product; reaction products; oxide electrolyte; containing gas; cell comprising; dielectric material; discharge plasma; barrier discharge; porous cathode; inlet stream; producing oxygen; porous anode; /422/
Citation Formats
Kong, Peter C, and Lessing, Paul A. Method and apparatus for producing oxygenates from hydrocarbons. United States: N. p., 1995.
Web.
Kong, Peter C, & Lessing, Paul A. Method and apparatus for producing oxygenates from hydrocarbons. United States.
Kong, Peter C, and Lessing, Paul A. Sun .
"Method and apparatus for producing oxygenates from hydrocarbons". United States. https://www.osti.gov/servlets/purl/869947.
@article{osti_869947,
title = {Method and apparatus for producing oxygenates from hydrocarbons},
author = {Kong, Peter C and Lessing, Paul A},
abstractNote = {A chemical reactor for oxygenating hydrocarbons includes: a) a dielectric barrier discharge plasma cell, the plasma cell comprising a pair of electrodes having a dielectric material and void therebetween, the plasma cell comprising a hydrocarbon gas inlet feeding to the void; b) a solid oxide electrochemical cell, the electrochemical cell comprising a solid oxide electrolyte positioned between a porous cathode and a porous anode, an oxygen containing gas inlet stream feeding to the porous cathode side of the electrochemical cell; c) a first gas passageway feeding from the void to the anode side of the electrochemical cell; and d) a gas outlet feeding from the anode side of the electrochemical cell to expel reaction products from the chemical reactor. A method of oxygenating hydrocarbons is also disclosed.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1995},
month = {1}
}
Works referenced in this record:
High temperature type proton conductor based on SrCeO3 and its application to solid electrolyte fuel cells
journal, December 1983
- Iwahara, Hiroyasu; Uchida, Hiroyuki; Tanaka, Shinichiro
- Solid State Ionics, Vol. 9-10
Electrochemical enhancement of oxidative coupling of methane over LiCl-doped NiO using stabilized zirconia electrolyte
journal, January 1988
- Otsuka, Kyoshi; Suga, Katsuo; Yamanaka, Ichiro
- Catalysis Letters, Vol. 1, Issue 12
Oxidation of methane in solid state electrochemical reactors
journal, September 1988
- Steele, B. C. H.; Kelly, I.; Middleton, H.
- Solid State Ionics, Vol. 28-30, Issue Part 2, p. 1547-1552
Soot elimination and NO/sub x/ and SO/sub x/ reduction in diesel-engine exhaust by a combination of discharge plasma and oil dynamics
journal, January 1992
- Higashi, M.; Uchida, S.; Suzuki, N.
- IEEE Transactions on Plasma Science, Vol. 20, Issue 1
Plasma Spraying of Porous Electrodes for a Planar Solid Oxide Fuel Cell
journal, March 1991
- Tai, Lone-Wen; Lessing, Paul A.
- Journal of the American Ceramic Society, Vol. 74, Issue 3
Catalytic partial oxidation of methane over barium metaplumbate BaPbO3: possible involvement of peroxide ion
journal, March 1989
- Kharas, Karl C. C.; Lunsford, Jack H.
- Journal of the American Chemical Society, Vol. 111, Issue 6
Methane Activation to C 2 Hydrocarbon Species in Solid Oxide Fuel Cell
journal, October 1988
- Pujare, Nirupama U.; Sammells, Anthony F.
- Journal of The Electrochemical Society, Vol. 135, Issue 10
Electrochemical Modification of Ag ‐ MgO Catalyst Electrodes during Methane Oxidation
journal, July 1986
- Seimanides, S.; Stoukides, M.
- Journal of The Electrochemical Society, Vol. 133, Issue 7
Proton Conduction in Sintered Oxides Based on BaCeO[sub 3]
journal, January 1988
- Iwahara, H.
- Journal of The Electrochemical Society, Vol. 135, Issue 2
Dependence of catalytic rates on catalyst work function
journal, February 1990
- Vayenas, C. G.; Bebelis, S.; Ladas, S.
- Nature, Vol. 343, Issue 6259
Electrocatalytic methane coupling in the absence of oxygen on a high-temperature proton-conducting electrolyte
journal, January 1991
- Woldman, L. S.; Sokolovskii, V. D.
- Catalysis Letters, Vol. 8, Issue 1