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Title: Partial oxidation process for producing a stream of hot purified gas

Abstract

A partial oxidation process for the production of a stream of hot clean gas substantially free from particulate matter, ammonia, alkali metal compounds, halides and sulfur-containing gas for use as synthesis gas, reducing gas, or fuel gas. A hydrocarbonaceous fuel comprising a solid carbonaceous fuel with or without liquid hydrocarbonaceous fuel or gaseous hydrocarbon fuel, wherein said hydrocarbonaceous fuel contains halides, alkali metal compounds, sulfur, nitrogen and inorganic ash containing components, is reacted in a gasifier by partial oxidation to produce a hot raw gas stream comprising H.sub.2, CO, CO.sub.2, H.sub.2 O, CH.sub.4, NH.sub.3, HCl, HF, H.sub.2 S, COS, N.sub.2, Ar, particulate matter, vapor phase alkali metal compounds, and molten slag. The hot raw gas stream from the gasifier is split into two streams which are separately deslagged, cleaned and recombined. Ammonia in the gas mixture is catalytically disproportionated into N.sub.2 and H.sub.2. The ammonia-free gas stream is then cooled and halides in the gas stream are reacted with a supplementary alkali metal compound to remove HCl and HF. Alkali metal halides, vaporized alkali metal compounds and residual fine particulate matter are removed from the gas stream by further cooling and filtering. The sulfur-containing gases in the process gas streammore » are then reacted at high temperature with a regenerable sulfur-reactive mixed metal oxide sulfur sorbent material to produce a sulfided sorbent material which is then separated from the hot clean purified gas stream having a temperature of at least 1000.degree. F.« less

Inventors:
 [1];  [2];  [3];  [4]
  1. Chino Hills, CA
  2. Anaheim, CA
  3. Torrance, CA
  4. Wappingers Falls, NY
Issue Date:
Research Org.:
Texaco Inc. (White Plains, NY)
OSTI Identifier:
869798
Patent Number(s):
5401282
Assignee:
Texaco Inc. (White Plains, NY)
DOE Contract Number:  
FC21-87MC23277
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
partial; oxidation; process; producing; stream; hot; purified; gas; production; clean; substantially; free; particulate; matter; ammonia; alkali; metal; compounds; halides; sulfur-containing; synthesis; reducing; fuel; hydrocarbonaceous; comprising; solid; carbonaceous; liquid; gaseous; hydrocarbon; contains; sulfur; nitrogen; inorganic; ash; containing; components; reacted; gasifier; produce; raw; nh; hcl; hf; cos; vapor; phase; molten; slag; split; streams; separately; deslagged; cleaned; recombined; mixture; catalytically; disproportionated; ammonia-free; cooled; supplementary; compound; remove; vaporized; residual; fine; removed; cooling; filtering; gases; temperature; regenerable; sulfur-reactive; mixed; oxide; sorbent; material; sulfided; separated; 1000; degree; sulfur sorbent; clean gas; gaseous hydrocarbon; fine particulate; containing gases; metal halides; reducing gas; liquid hydrocarbon; molten slag; metal compound; particulate matter; substantially free; process gas; partial oxidation; metal compounds; mixed metal; hydrocarbon fuel; fuel gas; alkali metal; metal oxide; gas stream; synthesis gas; metal halide; solid carbonaceous; gas mixture; containing gas; sorbent material; vapor phase; sulfur-containing gases; stream comprising; oxidation process; carbonaceous fuel; solid carbon; sulfided sorbent; sulfur-containing gas; purified gas; hydrocarbonaceous fuel; gas substantially; liquid hydrocarbonaceous; remove hcl; fuel contains; fuel comprising; ash containing; containing components; /48/60/252/423/

Citation Formats

Leininger, Thomas F, Robin, Allen M, Wolfenbarger, James K, and Suggitt, Robert M. Partial oxidation process for producing a stream of hot purified gas. United States: N. p., 1995. Web.
Leininger, Thomas F, Robin, Allen M, Wolfenbarger, James K, & Suggitt, Robert M. Partial oxidation process for producing a stream of hot purified gas. United States.
Leininger, Thomas F, Robin, Allen M, Wolfenbarger, James K, and Suggitt, Robert M. Sun . "Partial oxidation process for producing a stream of hot purified gas". United States. https://www.osti.gov/servlets/purl/869798.
@article{osti_869798,
title = {Partial oxidation process for producing a stream of hot purified gas},
author = {Leininger, Thomas F and Robin, Allen M and Wolfenbarger, James K and Suggitt, Robert M},
abstractNote = {A partial oxidation process for the production of a stream of hot clean gas substantially free from particulate matter, ammonia, alkali metal compounds, halides and sulfur-containing gas for use as synthesis gas, reducing gas, or fuel gas. A hydrocarbonaceous fuel comprising a solid carbonaceous fuel with or without liquid hydrocarbonaceous fuel or gaseous hydrocarbon fuel, wherein said hydrocarbonaceous fuel contains halides, alkali metal compounds, sulfur, nitrogen and inorganic ash containing components, is reacted in a gasifier by partial oxidation to produce a hot raw gas stream comprising H.sub.2, CO, CO.sub.2, H.sub.2 O, CH.sub.4, NH.sub.3, HCl, HF, H.sub.2 S, COS, N.sub.2, Ar, particulate matter, vapor phase alkali metal compounds, and molten slag. The hot raw gas stream from the gasifier is split into two streams which are separately deslagged, cleaned and recombined. Ammonia in the gas mixture is catalytically disproportionated into N.sub.2 and H.sub.2. The ammonia-free gas stream is then cooled and halides in the gas stream are reacted with a supplementary alkali metal compound to remove HCl and HF. Alkali metal halides, vaporized alkali metal compounds and residual fine particulate matter are removed from the gas stream by further cooling and filtering. The sulfur-containing gases in the process gas stream are then reacted at high temperature with a regenerable sulfur-reactive mixed metal oxide sulfur sorbent material to produce a sulfided sorbent material which is then separated from the hot clean purified gas stream having a temperature of at least 1000.degree. F.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1995},
month = {1}
}

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