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Title: Articles including thin film monolayers and multilayers

Abstract

Articles of manufacture including: (a) a base substrate having an oxide surface layer, and a multidentate ligand, capable of binding a metal ion, attached to the oxide surface layer of the base substrate, (b) a base substrate having an oxide surface layer, a multidentate ligand, capable of binding a metal ion, attached to the oxide surface layer of the base substrate, and a metal species attached to the multidentate ligand, (c) a base substrate having an oxide surface layer, a multidentate ligand, capable of binding a metal ion, attached to the oxide surface layer of the base substrate, a metal species attached to the multidentate ligand, and a multifunctional organic ligand attached to the metal species, and (d) a base substrate having an oxide surface layer, a multidentate ligand, capable of binding a metal ion, attached to the oxide surface layer of the base substrate, a metal species attached to the multidentate ligand, a multifunctional organic ligand attached to the metal species, and a second metal species attached to the multifunctional organic ligand, are provided, such articles useful in detecting the presence of a selected target species, as nonliear optical materials, or as scavengers for selected target species.

Inventors:
 [1];  [1]
  1. Los Alamos, NM
Issue Date:
Research Org.:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
OSTI Identifier:
869786
Patent Number(s):
5397642
Assignee:
United States of America as represented by United States (Washington, DC)
Patent Classifications (CPCs):
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
DOE Contract Number:  
W-7405-ENG-36
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
articles; including; film; monolayers; multilayers; manufacture; base; substrate; oxide; surface; layer; multidentate; ligand; capable; binding; metal; attached; species; multifunctional; organic; provided; useful; detecting; presence; selected; target; nonliear; optical; materials; scavengers; oxide surface; metal species; surface layer; optical materials; base substrate; articles including; organic ligand; selected target; articles useful; manufacture including; /428/210/

Citation Formats

Li, DeQuan, and Swanson, Basil I. Articles including thin film monolayers and multilayers. United States: N. p., 1995. Web.
Li, DeQuan, & Swanson, Basil I. Articles including thin film monolayers and multilayers. United States.
Li, DeQuan, and Swanson, Basil I. Sun . "Articles including thin film monolayers and multilayers". United States. https://www.osti.gov/servlets/purl/869786.
@article{osti_869786,
title = {Articles including thin film monolayers and multilayers},
author = {Li, DeQuan and Swanson, Basil I},
abstractNote = {Articles of manufacture including: (a) a base substrate having an oxide surface layer, and a multidentate ligand, capable of binding a metal ion, attached to the oxide surface layer of the base substrate, (b) a base substrate having an oxide surface layer, a multidentate ligand, capable of binding a metal ion, attached to the oxide surface layer of the base substrate, and a metal species attached to the multidentate ligand, (c) a base substrate having an oxide surface layer, a multidentate ligand, capable of binding a metal ion, attached to the oxide surface layer of the base substrate, a metal species attached to the multidentate ligand, and a multifunctional organic ligand attached to the metal species, and (d) a base substrate having an oxide surface layer, a multidentate ligand, capable of binding a metal ion, attached to the oxide surface layer of the base substrate, a metal species attached to the multidentate ligand, a multifunctional organic ligand attached to the metal species, and a second metal species attached to the multifunctional organic ligand, are provided, such articles useful in detecting the presence of a selected target species, as nonliear optical materials, or as scavengers for selected target species.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1995},
month = {1}
}

Works referenced in this record:

Inorganic analogs of Langmuir-Blodgett films: adsorption of ordered zirconium 1,10-decanebisphosphonate multilayers on silicon surfaces
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Self-assembling double layers on gold surfaces: the merging of two chemistries
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Incorporation of phenoxy groups in self-assembled monolayers of trichlorosilane derivatives. Effects on film thickness, wettability, and molecular orientation
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Polar Orientation of Dyes in Robust Multilayers by Zirconium Phosphate-Phosphonate Interlayers
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Chromophoric self-assembled multilayers. Organic superlattice approaches to thin-film nonlinear optical materials
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Ionic recognition and selective response in self-assembling monolayer membranes on electrodes
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Structure and reactivity of alkylsiloxane monolayers formed by reaction of alkyltrichlorosilanes on silicon substrates
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The formation of a crystalline monolayer of folded molecules by solution self-assembly of .alpha.,.omega.-alkanedioic acids on silver
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Self-assembly of organic multilayers with polar order using zirconium phosphate bonding between layers
journal, October 1990