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Title: Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation

Abstract

New compositions of matter comprising cyano-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has cyano groups attached thereto in meso and/or .beta.-pyrrolic positions.

Inventors:
 [1];  [2]
  1. (Downingtown, PA)
  2. Wallingford, PA
Issue Date:
Research Org.:
Sun Refining and Marketing Co., Marcus Hook, PA (United States)
OSTI Identifier:
869710
Patent Number(s):
5382662
Assignee:
Sun Company, Inc. (R&M) (Philadelphia, PA)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
DOE Contract Number:  
FC21-90MC26029
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
cyano-; polycyanometallo-porphyrins; catalysts; alkane; oxidation; compositions; matter; comprising; cyano-substituted; metal; complexes; porphyrins; alkanes; iron; chromium; manganese; ruthenium; copper; cobalt; porphyrin; cyano; attached; thereto; meso; beta; -pyrrolic; positions; alkane oxidation; matter comprising; attached thereto; metal complexes; metal complex; -pyrrolic positions; comprising cyano-substituted; cyano-substituted metal; /999/

Citation Formats

Ellis, Jr., Paul E., and Lyons, James E. Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation. United States: N. p., 1995. Web.
Ellis, Jr., Paul E., & Lyons, James E. Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation. United States.
Ellis, Jr., Paul E., and Lyons, James E. Sun . "Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation". United States. https://www.osti.gov/servlets/purl/869710.
@article{osti_869710,
title = {Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation},
author = {Ellis, Jr., Paul E. and Lyons, James E},
abstractNote = {New compositions of matter comprising cyano-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has cyano groups attached thereto in meso and/or .beta.-pyrrolic positions.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1995},
month = {1}
}

Patent:

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