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Title: Separation of metal ions from aqueous solutions

A process and apparatus for quantitatively and selectively separating metal ions from mixtures thereof in aqueous solution. The apparatus includes, in combination, a horizontal electrochemical flow cell containing flow bulk electrolyte solution and an aqueous, metal ion-containing solution, the cell containing a metal mesh working electrode, a counter electrode positioned downstream from the working electrode, an independent variable power supply/potentiostat positioned outside of the flow cell and connected to the electrodes, and optionally a detector such as a chromatographic detector, positioned outside the flow cell. This apparatus and its operation has significant application where trace amounts of metal ions are to be separated.
Inventors:
 [1]
  1. (Augusta, GA)
Issue Date:
OSTI Identifier:
869543
Assignee:
United States Department of Energy (Washington, DC) SRS
Patent Number(s):
US 5354438
Contract Number:
AC09-89SR18035
Research Org:
WESTINGHOUSE SAVANNAH RIVER CO
Country of Publication:
United States
Language:
English
Subject:
separation; metal; aqueous; solutions; process; apparatus; quantitatively; selectively; separating; mixtures; solution; combination; horizontal; electrochemical; flow; cell; containing; bulk; electrolyte; ion-containing; mesh; electrode; counter; positioned; downstream; independent; variable; power; supply; potentiostat; outside; connected; electrodes; optionally; detector; chromatographic; operation; significant; application; trace; amounts; separated; selectively separating; electrode positioned; metal mesh; aqueous solution; power supply; aqueous solutions; electrolyte solution; ion-containing solution; flow cell; counter electrode; cell containing; positioned outside; separating metal; trace amounts; trace amount; positioned downstream; variable power; containing solution; chemical flow; cell contain; electrode position; /205/204/