Synthesis of 1,3,3-trinitroazetidine
Abstract
A process of preparing 1,3,3-trinitroazetidine including forming a 5-hydroxymethyl-5-nitro-1-alkyltetrahydro-1,3-oxazine, e.g., reacting a 1,3,5-trialkyl hexahydrotriazine and tris(hydroxymethyl)nitromethane, ring opening said 5-hydroxymethyl-5-nitro-1-alkyltetrahydro-1,3-oxazine to form a 3-alkylamino-2-hydroxymethyl-2-nitro-1-propanol salt, ring closing said 3-alkylamino-2-hydroxymethyl-2-nitro-1-propanol salt to form a 3-hydroxymethyl-3-nitro-1-alkylazetidine salt, nitrating said 3-hydroxymethyl-3-nitro-1-alkylazetidine salt to form a 1-alkyl-3,3-dinitroazetidine, and converting said 1-alkyl-3,3-dinitroazetidine into 1,3,3-trinitroazetidine is disclosed.
- Inventors:
-
- Los Alamos, NM
- Issue Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- OSTI Identifier:
- 869438
- Patent Number(s):
- 5336784
- Assignee:
- Regents of University of California (Oakland, CA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
- DOE Contract Number:
- W-7405-ENG-36
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- synthesis; 3-trinitroazetidine; process; preparing; including; forming; 5-hydroxymethyl-5-nitro-1-alkyltetrahydro-1; 3-oxazine; reacting; 5-trialkyl; hexahydrotriazine; tris; hydroxymethyl; nitromethane; form; 3-alkylamino-2-hydroxymethyl-2-nitro-1-propanol; salt; closing; 3-hydroxymethyl-3-nitro-1-alkylazetidine; nitrating; 1-alkyl-3; 3-dinitroazetidine; converting; disclosed; including forming; /999/
Citation Formats
Hiskey, Michael A, and Coburn, Michael D. Synthesis of 1,3,3-trinitroazetidine. United States: N. p., 1994.
Web.
Hiskey, Michael A, & Coburn, Michael D. Synthesis of 1,3,3-trinitroazetidine. United States.
Hiskey, Michael A, and Coburn, Michael D. Sat .
"Synthesis of 1,3,3-trinitroazetidine". United States. https://www.osti.gov/servlets/purl/869438.
@article{osti_869438,
title = {Synthesis of 1,3,3-trinitroazetidine},
author = {Hiskey, Michael A and Coburn, Michael D},
abstractNote = {A process of preparing 1,3,3-trinitroazetidine including forming a 5-hydroxymethyl-5-nitro-1-alkyltetrahydro-1,3-oxazine, e.g., reacting a 1,3,5-trialkyl hexahydrotriazine and tris(hydroxymethyl)nitromethane, ring opening said 5-hydroxymethyl-5-nitro-1-alkyltetrahydro-1,3-oxazine to form a 3-alkylamino-2-hydroxymethyl-2-nitro-1-propanol salt, ring closing said 3-alkylamino-2-hydroxymethyl-2-nitro-1-propanol salt to form a 3-hydroxymethyl-3-nitro-1-alkylazetidine salt, nitrating said 3-hydroxymethyl-3-nitro-1-alkylazetidine salt to form a 1-alkyl-3,3-dinitroazetidine, and converting said 1-alkyl-3,3-dinitroazetidine into 1,3,3-trinitroazetidine is disclosed.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1994},
month = {1}
}
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