Conversion of fullerenes to diamond

Gruen, Dieter M

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Title: Conversion of fullerenes to diamond

Abstract

A method of forming synthetic diamond on a substrate. The method involves providing a substrate surface covered with a fullerene or diamond coating, positioning a fullerene in an ionization source, creating a fullerene vapor, ionizing fullerene molecules, accelerating the fullerene ions to energies above 250 eV to form a fullerene ion beam, impinging the fullerene ion beam on the substrate surface and continuing these steps to obtain a diamond film thickness on the substrate.

Inventors:

Gruen, Dieter M ^[1]

1324 59th St., Downers Grove, IL 60515

Issue Date:: 1994-01-01

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

OSTI Identifier:: 869386

Patent Number(s):: 5328676

Assignee:: Gruen, Dieter M. (1324 59th St., Downers Grove, IL 60515)

Patent Classifications (CPCs):: C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL

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C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B32/26 - Preparation

C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL
C23C14/0605 - {Carbon}
C23C14/0611 - {Diamond}
C23C14/221 - {Ion beam deposition
C23C16/27 - Diamond only
C23C16/274 - {using microwave discharges}
C23C16/277 - {using other elements in the gas phase besides carbon and hydrogen

C - CHEMISTRY C30 - CRYSTAL GROWTH C30B - SINGLE-CRYSTAL-GROWTH
C30B23/02 - Epitaxial-layer growth
C30B25/105 - {by irradiation or electric discharge}
C30B29/04 - Diamond
C30B33/00 - After-treatment of single crystals or homogeneous polycrystalline material with defined structure

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01J - ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
H01J9/025 - {of field emission cathodes}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10S - TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10S977/734 - Fullerenes, i.e. graphene-based structures, such as nanohorns, nanococoons, nanoscrolls or fullerene-like structures, e.g. WS2 or MoS2 chalcogenide nanotubes, planar C3N4, etc.

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Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: conversion; fullerenes; diamond; method; forming; synthetic; substrate; involves; providing; surface; covered; fullerene; coating; positioning; ionization; source; creating; vapor; ionizing; molecules; accelerating; energies; 250; form; beam; impinging; continuing; steps; obtain; film; thickness; forming synthetic; diamond coating; synthetic diamond; film thickness; method involves; substrate surface; diamond film; ionization source; involves providing; fullerene molecules; surface covered; fullerene vapor; method involve; surface cover; /423/204/427/

Citation Formats


                    Gruen, Dieter M. Conversion of fullerenes to diamond.  United States: N. p., 1994. 
        Web.

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                    Gruen, Dieter M. Conversion of fullerenes to diamond.  United States.

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                    Gruen, Dieter M. Sat .  
        "Conversion of fullerenes to diamond".  United States.  https://www.osti.gov/servlets/purl/869386.

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@article{osti_869386,

  title        = {Conversion of fullerenes to diamond},

  author       = {Gruen, Dieter M},

  abstractNote = {A method of forming synthetic diamond on a substrate. The method involves providing a substrate surface covered with a fullerene or diamond coating, positioning a fullerene in an ionization source, creating a fullerene vapor, ionizing fullerene molecules, accelerating the fullerene ions to energies above 250 eV to form a fullerene ion beam, impinging the fullerene ion beam on the substrate surface and continuing these steps to obtain a diamond film thickness on the substrate.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {1994},

  month        = {1}

}

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Works referenced in this record:

High-yield synthesis, separation, and mass-spectrometric characterization of fullerenes C60 to C266
journal, September 1991

Parker, Deborah Holmes; Wurz, Peter; Chatterjee, Kuntal
Journal of the American Chemical Society, Vol. 113, Issue 20
https://doi.org/10.1021/ja00020a008

Spectrometric Characterization of Purified C ₆₀ and C ₇₀
journal, January 1990

Lykke, Keith R.; Pellin, Michael J.; Wurz, Peter
MRS Proceedings, Vol. 206
https://doi.org/10.1557/PROC-206-679

Laser deposition of carbon clusters on surfaces: A new approach to the study of Fullerenes
journal, December 1990

Meijer, Gerard; Bethune, Donald S.
The Journal of Chemical Physics, Vol. 93, Issue 11
https://doi.org/10.1063/1.459360

Fullerenes
journal, October 1991

Curl, Robert F.; Smalley, Richard E.
Scientific American, Vol. 265, Issue 4
https://doi.org/10.1038/scientificamerican1091-54

Delayed electron emission from photoexcited C ₆₀
journal, November 1991

Wurz, Peter; Lykke, Keith R.
The Journal of Chemical Physics, Vol. 95, Issue 9
https://doi.org/10.1063/1.461046

Metastable Growth of Diamond and Diamond-Like Phases
journal, August 1991

Angus, J. C.; Wang, Y.; Sunkara, M.
Annual Review of Materials Science, Vol. 21, Issue 1
https://doi.org/10.1146/annurev.ms.21.080191.001253

Growth mechanism of vapor-deposited diamond
journal, February 1988

Frenklach, Michael; Spear, Karl E.
Journal of Materials Research, Vol. 3, Issue 1
https://doi.org/10.1557/JMR.1988.0133

Triplet states of fullerenes C60 and C70. Electron paramagnetic resonance spectra, photophysics, and electronic structures
journal, March 1991

Wasielewski, Michael R.; O'Neil, Michael P.; Lykke, Keith R.
Journal of the American Chemical Society, Vol. 113, Issue 7
https://doi.org/10.1021/ja00007a074

C60: Buckminsterfullerene
journal, September 1991

Kroto, H. W.; Allaf, A. W.; Balm, S. P.
Chemical Reviews, Vol. 91, Issue 6
https://doi.org/10.1021/cr00006a005

Resilience of all-carbon molecules C60, C70, and C84: a surface-scattering time-of-flight investigation
journal, October 1991

Beck, Rainer D.; St. John, Pamela; Alvarez, Marcos M.
The Journal of Physical Chemistry, Vol. 95, Issue 21
https://doi.org/10.1021/j100174a066

Solid C60: a new form of carbon
journal, September 1990

Krätschmer, W.; Lamb, Lowell D.; Fostiropoulos, K.
Nature, Vol. 347, Issue 6291
https://doi.org/10.1038/347354a0

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Similar Records

Title: Conversion of fullerenes to diamond

Abstract

Citation Formats

High-yield synthesis, separation, and mass-spectrometric characterization of fullerenes C60 to C266 journal, September 1991

Spectrometric Characterization of Purified C 60 and C 70 journal, January 1990

Laser deposition of carbon clusters on surfaces: A new approach to the study of Fullerenes journal, December 1990

Fullerenes journal, October 1991

Delayed electron emission from photoexcited C 60 journal, November 1991

Metastable Growth of Diamond and Diamond-Like Phases journal, August 1991

Growth mechanism of vapor-deposited diamond journal, February 1988

Triplet states of fullerenes C60 and C70. Electron paramagnetic resonance spectra, photophysics, and electronic structures journal, March 1991

C60: Buckminsterfullerene journal, September 1991

Resilience of all-carbon molecules C60, C70, and C84: a surface-scattering time-of-flight investigation journal, October 1991

Solid C60: a new form of carbon journal, September 1990

High-yield synthesis, separation, and mass-spectrometric characterization of fullerenes C60 to C266
journal, September 1991

Spectrometric Characterization of Purified C ₆₀ and C ₇₀
journal, January 1990

Laser deposition of carbon clusters on surfaces: A new approach to the study of Fullerenes
journal, December 1990

Fullerenes
journal, October 1991

Delayed electron emission from photoexcited C ₆₀
journal, November 1991

Metastable Growth of Diamond and Diamond-Like Phases
journal, August 1991

Growth mechanism of vapor-deposited diamond
journal, February 1988

Triplet states of fullerenes C60 and C70. Electron paramagnetic resonance spectra, photophysics, and electronic structures
journal, March 1991

C60: Buckminsterfullerene
journal, September 1991

Resilience of all-carbon molecules C60, C70, and C84: a surface-scattering time-of-flight investigation
journal, October 1991

Solid C60: a new form of carbon
journal, September 1990