Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode
Abstract
An improved rechargeable zinc cell is described comprising a zinc electrode and another electrode such as, for example, a nickel-containing electrode, and having an electrolyte containing KOH and a combination of KF and K.sub.2 CO.sub.3 salts which inhibits shape change in the zinc electrode, i.e., the zinc electrode exhibits low shape change, resulting in an improved capacity retention of the cell over an number of charge-discharge cycles, while still maintaining high discharge rate characteristics.
- Inventors:
-
- Berkeley, CA
- Orinda, CA
- Walnut Creek, CA
- Issue Date:
- Research Org.:
- Univ. of California (United States)
- OSTI Identifier:
- 869233
- Patent Number(s):
- 5302475
- Assignee:
- Regents of University of California (Oakland, CA)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- AC03-76SF00098
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- rechargeable; zinc; cell; alkaline; electrolyte; inhibits; shape; change; electrode; improved; described; comprising; example; nickel-containing; containing; koh; combination; kf; salts; exhibits; resulting; capacity; retention; charge-discharge; cycles; maintaining; discharge; rate; characteristics; alkaline electrolyte; zinc electrode; electrolyte containing; shape change; described comprising; charge cycle; rechargeable zinc; zinc cell; electrode exhibits; discharge cycle; discharge rate; inhibits shape; charge rate; nickel-containing electrode; improved capacity; improved rechargeable; charge-discharge cycle; /429/
Citation Formats
Adler, Thomas C, McLarnon, Frank R, and Cairns, Elton J. Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode. United States: N. p., 1994.
Web.
Adler, Thomas C, McLarnon, Frank R, & Cairns, Elton J. Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode. United States.
Adler, Thomas C, McLarnon, Frank R, and Cairns, Elton J. Sat .
"Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode". United States. https://www.osti.gov/servlets/purl/869233.
@article{osti_869233,
title = {Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode},
author = {Adler, Thomas C and McLarnon, Frank R and Cairns, Elton J},
abstractNote = {An improved rechargeable zinc cell is described comprising a zinc electrode and another electrode such as, for example, a nickel-containing electrode, and having an electrolyte containing KOH and a combination of KF and K.sub.2 CO.sub.3 salts which inhibits shape change in the zinc electrode, i.e., the zinc electrode exhibits low shape change, resulting in an improved capacity retention of the cell over an number of charge-discharge cycles, while still maintaining high discharge rate characteristics.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat Jan 01 00:00:00 EST 1994},
month = {Sat Jan 01 00:00:00 EST 1994}
}
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Works referenced in this record:
Zinc Electrode Cycle-Life Performance in Alkaline Electrolytes Having Reduced zinc Species Solubility
journal, August 1985
- Nichols, James T.; McLARNON, Frank R.; Cairns, Elton J.
- Chemical Engineering Communications, Vol. 37, Issue 1-6
The Secondary Alkaline Zinc Electrode
journal, January 1991
- McLarnon, Frank R.
- Journal of The Electrochemical Society, Vol. 138, Issue 2