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Title: Nonlinear optical and conductive polymeric material

Abstract

A polymeric material which exhibits nonlinear optical properties if undoped and conductive properties if doped. The polymer is prepared by polymerizing diethynylsilane compositions, the resulting polymeric material having a weight average molecular weight between about 20,000 and about 200,000 grams per mole. The polymer is prepared and catalytically polymerized by exposure to a catalyst, such as MoCl.sub.5 or W(CO).sub.6 /hv.

Inventors:
 [1];  [1];  [1]
  1. Ames, IA
Issue Date:
Research Org.:
Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States)
OSTI Identifier:
868966
Patent Number(s):
5254289
Application Number:
07/877,925
Assignee:
Iowa State University (Ames, IA)
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01B - CABLES
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08F - MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
DOE Contract Number:  
W-7405-ENG-82
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
nonlinear; optical; conductive; polymeric; material; exhibits; properties; undoped; doped; polymer; prepared; polymerizing; diethynylsilane; compositions; resulting; weight; average; molecular; 20; 000; 200; grams; mole; catalytically; polymerized; exposure; catalyst; mocl; hv; average molecular; polymeric material; molecular weight; nonlinear optical; optical properties; conductive polymer; conductive properties; resulting polymer; nonlinear optic; exhibits nonlinear; polymerizing diethynylsilane; diethynylsilane compositions; conductive polymeric; /252/

Citation Formats

Barton, Thomas J, Ijadi-Maghsoodi, Sina, and Pang, Yi. Nonlinear optical and conductive polymeric material. United States: N. p., 1993. Web.
Barton, Thomas J, Ijadi-Maghsoodi, Sina, & Pang, Yi. Nonlinear optical and conductive polymeric material. United States.
Barton, Thomas J, Ijadi-Maghsoodi, Sina, and Pang, Yi. Fri . "Nonlinear optical and conductive polymeric material". United States. https://www.osti.gov/servlets/purl/868966.
@article{osti_868966,
title = {Nonlinear optical and conductive polymeric material},
author = {Barton, Thomas J and Ijadi-Maghsoodi, Sina and Pang, Yi},
abstractNote = {A polymeric material which exhibits nonlinear optical properties if undoped and conductive properties if doped. The polymer is prepared by polymerizing diethynylsilane compositions, the resulting polymeric material having a weight average molecular weight between about 20,000 and about 200,000 grams per mole. The polymer is prepared and catalytically polymerized by exposure to a catalyst, such as MoCl.sub.5 or W(CO).sub.6 /hv.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1993},
month = {1}
}

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