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Title: Process for catalytically oxidizing cycloolefins, particularly cyclohexene

Abstract

This invention is a process for catalytically oxidizing cycloolefins, particularly cyclohexenes, to form a variety of oxygenates. The catalyst used in the process is a covalently bonded iridium-heteropolyanion species. The process uses the catalyst in conjunction with a gaseous oxygen containing gas to form 2-cyclohexen-1-ol and also 2-cyclohexen-1-one.

Inventors:
 [1];  [2];  [3]
+ Show Inventor Affiliations
  1. Sapporo, JP
  2. Bend, OR
  3. Eugene, OR
Issue Date:
Research Org.:
University of Oregon (Eugene, OR)
OSTI Identifier:
868949
Patent Number(s):
5250739
Assignee:
Catalytica, Inc. (Mountain View, CA)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
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DOE Contract Number:  
FG06-89ER13998
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
process; catalytically; oxidizing; cycloolefins; particularly; cyclohexene; cyclohexenes; form; variety; oxygenates; catalyst; covalently; bonded; iridium-heteropolyanion; species; conjunction; gaseous; oxygen; containing; gas; 2-cyclohexen-1-ol; 2-cyclohexen-1-one; oxygen containing; containing gas; covalently bonded; anion species; catalytically oxidizing; oxidizing cycloolefins; particularly cyclohexene; /999/

Citation Formats

Mizuno, Noritaka, Lyon, David K, and Finke, Richard G. Process for catalytically oxidizing cycloolefins, particularly cyclohexene. United States: N. p., 1993. Web.
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Mizuno, Noritaka, Lyon, David K, & Finke, Richard G. Process for catalytically oxidizing cycloolefins, particularly cyclohexene. United States.
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Mizuno, Noritaka, Lyon, David K, and Finke, Richard G. Fri . "Process for catalytically oxidizing cycloolefins, particularly cyclohexene". United States. https://www.osti.gov/servlets/purl/868949.
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@article{osti_868949,
title = {Process for catalytically oxidizing cycloolefins, particularly cyclohexene},
author = {Mizuno, Noritaka and Lyon, David K and Finke, Richard G},
abstractNote = {This invention is a process for catalytically oxidizing cycloolefins, particularly cyclohexenes, to form a variety of oxygenates. The catalyst used in the process is a covalently bonded iridium-heteropolyanion species. The process uses the catalyst in conjunction with a gaseous oxygen containing gas to form 2-cyclohexen-1-ol and also 2-cyclohexen-1-one.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1993},
month = {1}
}
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