Process for production desulfurized of synthesis gas
Abstract
A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1900.degree.-2600.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises a calcium-containing compound portion, a sodium-containing compound portion, and a fluoride-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (1) a sulfur-containing sodium-calcium-fluoride silicate phase; and (2) a sodium-calcium sulfide phase.
- Inventors:
-
- Torrance, CA
- Wappingers Falls, NY
- Issue Date:
- Research Org.:
- Texaco Inc. (White Plains, NY)
- OSTI Identifier:
- 868945
- Patent Number(s):
- 5250083
- Assignee:
- Texaco Inc. (White Plains, NY)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10S - TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- DOE Contract Number:
- FC21-87MC23277
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- process; production; desulfurized; synthesis; gas; partial; oxidation; sulfur-; silicate-containing; carbonaceous; fuel; produce; reduced; sulfur; content; comprises; partially; oxidizing; temperature; range; 1900; degree; -2600; presence; moderator; oxygen-containing; capture; additive; calcium-containing; compound; portion; sodium-containing; fluoride-containing; comprising; molten; slag; sulfur-containing; sodium-calcium-fluoride; silicate; phase; sodium-calcium; sulfide; reduced sulfur; containing compound; molten slag; sulfur content; partial oxidation; oxygen-containing gas; synthesis gas; containing gas; gas comprising; containing carbon; carbonaceous fuel; calcium sulfide; partially oxidizing; containing sodium; sulfur capture; silicate-containing carbonaceous; comprises partially; containing carbonaceous; /48/252/
Citation Formats
Wolfenbarger, James K, and Najjar, Mitri S. Process for production desulfurized of synthesis gas. United States: N. p., 1993.
Web.
Wolfenbarger, James K, & Najjar, Mitri S. Process for production desulfurized of synthesis gas. United States.
Wolfenbarger, James K, and Najjar, Mitri S. Fri .
"Process for production desulfurized of synthesis gas". United States. https://www.osti.gov/servlets/purl/868945.
@article{osti_868945,
title = {Process for production desulfurized of synthesis gas},
author = {Wolfenbarger, James K and Najjar, Mitri S},
abstractNote = {A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1900.degree.-2600.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises a calcium-containing compound portion, a sodium-containing compound portion, and a fluoride-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (1) a sulfur-containing sodium-calcium-fluoride silicate phase; and (2) a sodium-calcium sulfide phase.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1993},
month = {1}
}
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