Process of .sup.196 Hg enrichment
Abstract
A simple rate equation model shows that by increasing the length of the photochemical reactor and/or by increasing the photon intensity in said reactor, the feedstock utilization of .sup.196 Hg will be increased. Two preferred embodiments of the present invention are described, namely (1) long reactors using long photochemical lamps and vapor filters; and (2) quartz reactors with external UV reflecting films. These embodiments have each been constructed and operated, demonstrating the enhanced utilization process dictated by the mathematical model (also provided).
- Inventors:
-
- Belmont, MA
- Salem, MA
- Issue Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- OSTI Identifier:
- 868759
- Patent Number(s):
- 5205913
- Assignee:
- GTE Products Corporation (Danvers, MA)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
- DOE Contract Number:
- AC03-76SF00098
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- process; 196; hg; enrichment; simple; rate; equation; model; increasing; length; photochemical; reactor; photon; intensity; feedstock; utilization; increased; preferred; embodiments; described; namely; reactors; lamps; vapor; filters; quartz; external; reflecting; films; constructed; operated; demonstrating; enhanced; dictated; mathematical; provided; chemical reactor; photochemical reactor; preferred embodiments; preferred embodiment; mathematical model; reflecting film; quartz reactor; rate equation; vapor filter; /204/
Citation Formats
Grossman, Mark W, and Mellor, Charles E. Process of .sup.196 Hg enrichment. United States: N. p., 1993.
Web.
Grossman, Mark W, & Mellor, Charles E. Process of .sup.196 Hg enrichment. United States.
Grossman, Mark W, and Mellor, Charles E. Fri .
"Process of .sup.196 Hg enrichment". United States. https://www.osti.gov/servlets/purl/868759.
@article{osti_868759,
title = {Process of .sup.196 Hg enrichment},
author = {Grossman, Mark W and Mellor, Charles E},
abstractNote = {A simple rate equation model shows that by increasing the length of the photochemical reactor and/or by increasing the photon intensity in said reactor, the feedstock utilization of .sup.196 Hg will be increased. Two preferred embodiments of the present invention are described, namely (1) long reactors using long photochemical lamps and vapor filters; and (2) quartz reactors with external UV reflecting films. These embodiments have each been constructed and operated, demonstrating the enhanced utilization process dictated by the mathematical model (also provided).},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Fri Jan 01 00:00:00 EST 1993},
month = {Fri Jan 01 00:00:00 EST 1993}
}
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Works referenced in this record:
Energy Conservation Through More Efficient Lighting
journal, October 1984
- Maya, J.; Grossman, M. W.; Lagushenko, R.
- Science, Vol. 226, Issue 4673
Photochemical isotope separation of mercury-196 by reaction with hydrogen halides
journal, May 1981
- Webster, Christopher R.; Zare, Richard N.
- The Journal of Physical Chemistry, Vol. 85, Issue 10