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Title: Poly(silylene)vinylenes from ethynylhydridosilanes

Abstract

Catalytic polymerization of dialkyl-, alkylaryl- or diaryldiethynylhydridosilanes cleanly affords soluble poly(silylene)vinylenes which can be shaped as fibers, films and bulk objects and thermally converted to silicon carbide.

Inventors:
 [1];  [1]
  1. Ames, IA
Issue Date:
Research Org.:
Ames Laboratory (AMES), Ames, IA; Iowa State Univ., Ames, IA (United States)
OSTI Identifier:
868534
Patent Number(s):
5162478
Application Number:
07/583,163
Assignee:
Iowa State University Research Foundation, Inc. (Ames, IA)
Patent Classifications (CPCs):
C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
DOE Contract Number:  
W-7405-ENG-82
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
poly; silylene; vinylenes; ethynylhydridosilanes; catalytic; polymerization; dialkyl-; alkylaryl-; diaryldiethynylhydridosilanes; cleanly; affords; soluble; shaped; fibers; films; bulk; thermally; converted; silicon; carbide; silicon carbide; thermally converted; soluble poly; /528/999/

Citation Formats

Barton, Thomas J, and Ijadi-Maghsoodi, Sina. Poly(silylene)vinylenes from ethynylhydridosilanes. United States: N. p., 1992. Web.
Barton, Thomas J, & Ijadi-Maghsoodi, Sina. Poly(silylene)vinylenes from ethynylhydridosilanes. United States.
Barton, Thomas J, and Ijadi-Maghsoodi, Sina. Tue . "Poly(silylene)vinylenes from ethynylhydridosilanes". United States. https://www.osti.gov/servlets/purl/868534.
@article{osti_868534,
title = {Poly(silylene)vinylenes from ethynylhydridosilanes},
author = {Barton, Thomas J and Ijadi-Maghsoodi, Sina},
abstractNote = {Catalytic polymerization of dialkyl-, alkylaryl- or diaryldiethynylhydridosilanes cleanly affords soluble poly(silylene)vinylenes which can be shaped as fibers, films and bulk objects and thermally converted to silicon carbide.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1992},
month = {11}
}