Hydrocracking of carbohydrates making glycerol, glycols and other polyols
Abstract
A homogeneous process for hydrocracking of carbohydrates in the presence of soluble transition metal hydrogenation catalyst with the production of lower polyhydric alcohols. A carbohydrate is contacted with hydrogen in the presence of a soluble transition metal catalyst and a strong base at a temperature of from about 25.degree. C. to about 200.degree. C. and a pressure of from about 15 to about 3000 psi.
- Inventors:
-
- Ridge, NY
- Corpus Christi, TX
- Issue Date:
- Research Org.:
- Associated Universities, Inc., Upton, NY (United States)
- OSTI Identifier:
- 867887
- Patent Number(s):
- 5026927
- Assignee:
- United States of America as represented by United States (Washington, DC)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
- DOE Contract Number:
- AC02-76CH00016
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- hydrocracking; carbohydrates; glycerol; glycols; polyols; homogeneous; process; presence; soluble; transition; metal; hydrogenation; catalyst; production; polyhydric; alcohols; carbohydrate; contacted; hydrogen; strong; base; temperature; 25; degree; 200; pressure; 15; 3000; psi; hydrogenation catalyst; transition metal; metal catalyst; strong base; polyhydric alcohol; metal hydrogenation; metal hydrogen; polyhydric alcohols; /999/
Citation Formats
Andrews, Mark A, and Klaeren, Stephen A. Hydrocracking of carbohydrates making glycerol, glycols and other polyols. United States: N. p., 1991.
Web.
Andrews, Mark A, & Klaeren, Stephen A. Hydrocracking of carbohydrates making glycerol, glycols and other polyols. United States.
Andrews, Mark A, and Klaeren, Stephen A. Tue .
"Hydrocracking of carbohydrates making glycerol, glycols and other polyols". United States. https://www.osti.gov/servlets/purl/867887.
@article{osti_867887,
title = {Hydrocracking of carbohydrates making glycerol, glycols and other polyols},
author = {Andrews, Mark A and Klaeren, Stephen A},
abstractNote = {A homogeneous process for hydrocracking of carbohydrates in the presence of soluble transition metal hydrogenation catalyst with the production of lower polyhydric alcohols. A carbohydrate is contacted with hydrogen in the presence of a soluble transition metal catalyst and a strong base at a temperature of from about 25.degree. C. to about 200.degree. C. and a pressure of from about 15 to about 3000 psi.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 01 00:00:00 EST 1991},
month = {Tue Jan 01 00:00:00 EST 1991}
}
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