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Title: Combined goal gasifier and fuel cell system and method

Abstract

A molten carbonate fuel cell is combined with a catalytic coal or coal char gasifier for providing the reactant gases comprising hydrogen, carbon monoxide and carbon dioxide used in the operation of the fuel cell. These reactant gases are stripped of sulfur compounds and particulate material and are then separated in discrete gas streams for conveyance to appropriate electrodes in the fuel cell. The gasifier is arranged to receive the reaction products generated at the anode of the fuel cell by the electricity-producing electrochemical reaction therein. These reaction products from the anode are formed primarily of high temperature steam and carbon dioxide to provide the steam, the atmosphere and the heat necessary to endothermically pyrolyze the coal or char in the presence of a catalyst. The reaction products generated at the cathode are substantially formed of carbon dioxide which is used to heat air being admixed with the carbon dioxide stream from the gasifier for providing the oxygen required for the reaction in the fuel cell and for driving an expansion device for energy recovery. A portion of this carbon dioxide from the cathode may be recycled into the fuel cell with the air-carbon dioxide mixture.

Inventors:
 [1];  [2]
  1. Morgantown, WV
  2. New Alexandria, PA
Issue Date:
Research Org.:
National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV (United States)
OSTI Identifier:
867363
Patent Number(s):
4921765
Assignee:
United States of America as represented by United States (Washington, DC)
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
combined; goal; gasifier; fuel; cell; method; molten; carbonate; catalytic; coal; char; providing; reactant; gases; comprising; hydrogen; carbon; monoxide; dioxide; operation; stripped; sulfur; compounds; particulate; material; separated; discrete; gas; streams; conveyance; appropriate; electrodes; arranged; receive; reaction; products; generated; anode; electricity-producing; electrochemical; therein; formed; primarily; temperature; steam; provide; atmosphere; heat; endothermically; pyrolyze; presence; catalyst; cathode; substantially; air; admixed; stream; oxygen; required; driving; expansion; device; energy; recovery; portion; recycled; air-carbon; mixture; gases comprising; temperature steam; catalytic coal; fuel cell; reactant gases; particulate material; carbon dioxide; carbon monoxide; gas stream; gas streams; chemical reaction; reaction product; carbonate fuel; reaction products; molten carbonate; reactant gas; energy recovery; sulfur compounds; expansion device; electrochemical reaction; comprising hydrogen; coal char; oxide mixture; sulfur compound; discrete gas; /429/

Citation Formats

Gmeindl, Frank D, and Geisbrecht, Rodney A. Combined goal gasifier and fuel cell system and method. United States: N. p., 1990. Web.
Gmeindl, Frank D, & Geisbrecht, Rodney A. Combined goal gasifier and fuel cell system and method. United States.
Gmeindl, Frank D, and Geisbrecht, Rodney A. Mon . "Combined goal gasifier and fuel cell system and method". United States. https://www.osti.gov/servlets/purl/867363.
@article{osti_867363,
title = {Combined goal gasifier and fuel cell system and method},
author = {Gmeindl, Frank D and Geisbrecht, Rodney A},
abstractNote = {A molten carbonate fuel cell is combined with a catalytic coal or coal char gasifier for providing the reactant gases comprising hydrogen, carbon monoxide and carbon dioxide used in the operation of the fuel cell. These reactant gases are stripped of sulfur compounds and particulate material and are then separated in discrete gas streams for conveyance to appropriate electrodes in the fuel cell. The gasifier is arranged to receive the reaction products generated at the anode of the fuel cell by the electricity-producing electrochemical reaction therein. These reaction products from the anode are formed primarily of high temperature steam and carbon dioxide to provide the steam, the atmosphere and the heat necessary to endothermically pyrolyze the coal or char in the presence of a catalyst. The reaction products generated at the cathode are substantially formed of carbon dioxide which is used to heat air being admixed with the carbon dioxide stream from the gasifier for providing the oxygen required for the reaction in the fuel cell and for driving an expansion device for energy recovery. A portion of this carbon dioxide from the cathode may be recycled into the fuel cell with the air-carbon dioxide mixture.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1990},
month = {1}
}