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Title: Process for introducing electrical conductivity into high-temperature polymeric materials

Abstract

High-temperature electrically conducting polymers. The in situ reactions: AgNO.sub.3 +RCHO.fwdarw.AG.sup.0 +RCOOH and R.sub.3 M.fwdarw.M.sup.0 3R, where M=Au or Pt have been found to introduce either substantial bulk or surface conductivity in high-temperature polymers. The reactions involving the R.sub.3 M were caused to proceed thermally suggesting the possibility of using laser means for initiating such reactions in selected areas or volumes of the polymeric materials. The polymers successfully investigated to date are polyphenylquinoxaline, polytolylquinoxaline, polyquinoline, polythiazole, and pyrrone.

Inventors:
 [1];  [2];  [1]
  1. Los Alamos, NM
  2. Jemez Springs, NM
Issue Date:
Research Org.:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
OSTI Identifier:
867149
Patent Number(s):
4876032
Assignee:
United States of America as represented by United States (Washington, DC)
Patent Classifications (CPCs):
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01B - CABLES
DOE Contract Number:  
W-7405-ENG-36
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
process; introducing; electrical; conductivity; high-temperature; polymeric; materials; electrically; conducting; polymers; situ; reactions; agno; rcho; fwdarw; rcooh; 3r; found; introduce; substantial; bulk; surface; involving; caused; proceed; thermally; suggesting; possibility; laser; means; initiating; selected; volumes; successfully; investigated; date; polyphenylquinoxaline; polytolylquinoxaline; polyquinoline; polythiazole; pyrrone; conducting polymers; laser means; polymeric materials; polymeric material; electrically conducting; electrical conductivity; conducting polymer; substantial bulk; situ reactions; temperature polymer; high-temperature electrically; high-temperature polymeric; introducing electrical; /252/

Citation Formats

Liepins, Raimond, Jorgensen, Betty S, and Liepins, Leila Z. Process for introducing electrical conductivity into high-temperature polymeric materials. United States: N. p., 1989. Web.
Liepins, Raimond, Jorgensen, Betty S, & Liepins, Leila Z. Process for introducing electrical conductivity into high-temperature polymeric materials. United States.
Liepins, Raimond, Jorgensen, Betty S, and Liepins, Leila Z. Sun . "Process for introducing electrical conductivity into high-temperature polymeric materials". United States. https://www.osti.gov/servlets/purl/867149.
@article{osti_867149,
title = {Process for introducing electrical conductivity into high-temperature polymeric materials},
author = {Liepins, Raimond and Jorgensen, Betty S and Liepins, Leila Z},
abstractNote = {High-temperature electrically conducting polymers. The in situ reactions: AgNO.sub.3 +RCHO.fwdarw.AG.sup.0 +RCOOH and R.sub.3 M.fwdarw.M.sup.0 3R, where M=Au or Pt have been found to introduce either substantial bulk or surface conductivity in high-temperature polymers. The reactions involving the R.sub.3 M were caused to proceed thermally suggesting the possibility of using laser means for initiating such reactions in selected areas or volumes of the polymeric materials. The polymers successfully investigated to date are polyphenylquinoxaline, polytolylquinoxaline, polyquinoline, polythiazole, and pyrrone.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1989},
month = {1}
}