Process for recovery of hydrogen and
Abstract
on of sulfur Abstract A process of abstracting sulfur from H.sub.2 S and generating hydrogen is disclosed comprising dissolving Pd.sub.2 X.sub.2 (.mu.-dppm).sub.2 in a solvent and then introducing H.sub.2 S. The palladium complex abstracts sulfur, forming hydrogen and a (.mu.-S) complex. The (.mu.-S) complex is readily oxidizable to a (.mu.-SO.sub.2) adduct which spontaneously loses SO.sub.2 and regenerates the palladium complex.
- Inventors:
-
- Vancouver, CA
- Richland, WA
- Issue Date:
- Research Org.:
- Battelle Memorial Institute, Columbus, OH (United States)
- OSTI Identifier:
- 866360
- Patent Number(s):
- 4693875
- Assignee:
- Battelle Memorial Institute (Richland, WA)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
- DOE Contract Number:
- AC06-76RL01830
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- process; recovery; hydrogen; sulfur; abstracting; generating; disclosed; comprising; dissolving; pd; -dppm; solvent; introducing; palladium; complex; abstracts; forming; -s; readily; oxidizable; -so; adduct; spontaneously; loses; regenerates; disclosed comprising; readily oxidizable; forming hydrogen; generating hydrogen; /423/999/987/
Citation Formats
James, Brian R, Li-Lee, Chung, Lilga, Michael A, and Nelson, David A. Process for recovery of hydrogen and. United States: N. p., 1987.
Web.
James, Brian R, Li-Lee, Chung, Lilga, Michael A, & Nelson, David A. Process for recovery of hydrogen and. United States.
James, Brian R, Li-Lee, Chung, Lilga, Michael A, and Nelson, David A. Thu .
"Process for recovery of hydrogen and". United States. https://www.osti.gov/servlets/purl/866360.
@article{osti_866360,
title = {Process for recovery of hydrogen and},
author = {James, Brian R and Li-Lee, Chung and Lilga, Michael A and Nelson, David A},
abstractNote = {on of sulfur Abstract A process of abstracting sulfur from H.sub.2 S and generating hydrogen is disclosed comprising dissolving Pd.sub.2 X.sub.2 (.mu.-dppm).sub.2 in a solvent and then introducing H.sub.2 S. The palladium complex abstracts sulfur, forming hydrogen and a (.mu.-S) complex. The (.mu.-S) complex is readily oxidizable to a (.mu.-SO.sub.2) adduct which spontaneously loses SO.sub.2 and regenerates the palladium complex.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Jan 01 00:00:00 EST 1987},
month = {Thu Jan 01 00:00:00 EST 1987}
}
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