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Title: Apparatus for use in sulfide chemiluminescence detection

Abstract

A method of chemiluminescently determining a sulfide which is either hydrogen sulfide or methyl mercaptan by reacting the sulfide with chlorine dioxide at low pressure and under conditions which allow a longer reaction time in emission of a single photon for every two sulfide containing species, and thereafter, chemiluminescently detecting and determining the sulfide. The invention also relates not only to the detection method, but the novel chemical reaction and a specifically designed chemiluminescence detection cell for the reaction.

Inventors:
 [1];  [1]
  1. Ames, IA
Issue Date:
Research Org.:
Ames Laboratory (AMES), Ames, IA
Sponsoring Org.:
USDOE
OSTI Identifier:
866101
Patent Number(s):
4634574
Assignee:
Iowa State Research Foundation, Inc. (Ames, IA)
Patent Classifications (CPCs):
G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
DOE Contract Number:  
W-7405-ENG-82
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
apparatus; sulfide; chemiluminescence; detection; method; chemiluminescently; determining; hydrogen; methyl; mercaptan; reacting; chlorine; dioxide; pressure; conditions; allow; reaction; time; emission; single; photon; containing; species; thereafter; detecting; relates; novel; chemical; specifically; designed; cell; chemiluminescence detection; detection method; chemical reaction; hydrogen sulfide; specifically designed; single photon; novel chemical; methyl mercaptan; chlorine dioxide; chemiluminescently determining; chemiluminescently detecting; reaction time; containing species; sulfide containing; designed chemiluminescence; detection cell; sulfide chemiluminescence; /422/362/366/436/

Citation Formats

Spurlin, Stanford R, and Yeung, Edward S. Apparatus for use in sulfide chemiluminescence detection. United States: N. p., 1987. Web.
Spurlin, Stanford R, & Yeung, Edward S. Apparatus for use in sulfide chemiluminescence detection. United States.
Spurlin, Stanford R, and Yeung, Edward S. Thu . "Apparatus for use in sulfide chemiluminescence detection". United States. https://www.osti.gov/servlets/purl/866101.
@article{osti_866101,
title = {Apparatus for use in sulfide chemiluminescence detection},
author = {Spurlin, Stanford R and Yeung, Edward S},
abstractNote = {A method of chemiluminescently determining a sulfide which is either hydrogen sulfide or methyl mercaptan by reacting the sulfide with chlorine dioxide at low pressure and under conditions which allow a longer reaction time in emission of a single photon for every two sulfide containing species, and thereafter, chemiluminescently detecting and determining the sulfide. The invention also relates not only to the detection method, but the novel chemical reaction and a specifically designed chemiluminescence detection cell for the reaction.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Jan 01 00:00:00 EST 1987},
month = {Thu Jan 01 00:00:00 EST 1987}
}