Hydrodesulfurization catalysis by Chevrel phase compounds

McCarty, Kevin F; Schrader, Glenn L

Title: Hydrodesulfurization catalysis by Chevrel phase compounds

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Abstract

A process is disclosed for the hydrodesulfurization of sulfur-containing hydrocarbon fuel with reduced ternary molybdenum sulfides, known as Chevrel phase compounds. Chevrel phase compounds of the general composition M.sub.x Mo.sub.6 S.sub.8, with M being Ho, Pb, Sn, Ag, In, Cu, Fe, Ni, or Co, were found to have hydrodesulfurization activities comparable to model unpromoted and cobalt-promoted MoS.sub.2 catalysts. The most active catalysts were the "large" cation compounds (Ho, Pb, Sn), and the least active catalysts were the "small" cation compounds (Cu, Fe, Ni, Co.).

Inventors:

McCarty, Kevin F ^[1]; Schrader, Glenn L ^[2]

Livermore, CA
Ames, IA

Issue Date:: 1985-12-24

Research Org.:: Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States)

OSTI Identifier:: 865711

Patent Number(s):: 4560470

Application Number:: 06/736,154

Assignee:: United States of America as represented by United States (Washington, DC)

Patent Classifications (CPCs):: C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

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C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G45/04 - characterised by the catalyst used

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J27/0515 - {with iron group metals or platinum group metals}
B01J27/051 - Molybdenum

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G45/08 - in combination with chromium, molybdenum, or tungsten metals, or compounds thereof

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DOE Contract Number:: W-7405-ENG-82

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: hydrodesulfurization; catalysis; chevrel; phase; compounds; process; disclosed; sulfur-containing; hydrocarbon; fuel; reduced; ternary; molybdenum; sulfides; composition; pb; cu; found; activities; comparable; model; unpromoted; cobalt-promoted; catalysts; active; cation; active catalyst; hydrocarbon fuel; reduced ternary; molybdenum sulfide; ternary molybdenum; molybdenum sulfides; phase compounds; active catalysts; chevrel phase; containing hydrocarbon; /208/502/

Citation Formats


                    McCarty, Kevin F, and Schrader, Glenn L. Hydrodesulfurization catalysis by Chevrel phase compounds.  United States: N. p., 1985. 
        Web.

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                    McCarty, Kevin F, & Schrader, Glenn L. Hydrodesulfurization catalysis by Chevrel phase compounds.  United States.

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                    McCarty, Kevin F, and Schrader, Glenn L. Tue .  
        "Hydrodesulfurization catalysis by Chevrel phase compounds".  United States.  https://www.osti.gov/servlets/purl/865711.

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@article{osti_865711,

  title        = {Hydrodesulfurization catalysis by Chevrel phase compounds},

  author       = {McCarty, Kevin F and Schrader, Glenn L},

  abstractNote = {A process is disclosed for the hydrodesulfurization of sulfur-containing hydrocarbon fuel with reduced ternary molybdenum sulfides, known as Chevrel phase compounds. Chevrel phase compounds of the general composition M.sub.x Mo.sub.6 S.sub.8, with M being Ho, Pb, Sn, Ag, In, Cu, Fe, Ni, or Co, were found to have hydrodesulfurization activities comparable to model unpromoted and cobalt-promoted MoS.sub.2 catalysts. The most active catalysts were the "large" cation compounds (Ho, Pb, Sn), and the least active catalysts were the "small" cation compounds (Cu, Fe, Ni, Co.).},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {1985},

  month        = {12}

}

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