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Title: Sulfide chemiluminescence detection

Abstract

A method of chemiluminescently determining a sulfide which is either hydrogen sulfide or methyl mercaptan by reacting the sulfide with chlorine dioxide at low pressure and under conditions which allow a longer reaction time in emission of a single photon for every two sulfide containing species, and thereafter, chemiluminescently detecting and determining the sulfide. The invention also relates not only to the detection method, but the novel chemical reaction and a specifically designed chemiluminescence detection cell for the reaction.

Inventors:
 [1];  [1]
  1. Ames, IA
Issue Date:
Research Org.:
Ames Laboratory (AMES), Ames, IA
Sponsoring Org.:
USDOE
OSTI Identifier:
865685
Patent Number(s):
4555491
Assignee:
Iowa State University Research Foundation, Inc. (Ames, IA)
Patent Classifications (CPCs):
G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
DOE Contract Number:  
W-7405-ENG-82
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
sulfide; chemiluminescence; detection; method; chemiluminescently; determining; hydrogen; methyl; mercaptan; reacting; chlorine; dioxide; pressure; conditions; allow; reaction; time; emission; single; photon; containing; species; thereafter; detecting; relates; novel; chemical; specifically; designed; cell; chemiluminescence detection; detection method; chemical reaction; hydrogen sulfide; specifically designed; single photon; novel chemical; methyl mercaptan; chlorine dioxide; chemiluminescently determining; chemiluminescently detecting; reaction time; containing species; sulfide containing; designed chemiluminescence; detection cell; sulfide chemiluminescence; /436/

Citation Formats

Spurlin, Stanford R, and Yeung, Edward S. Sulfide chemiluminescence detection. United States: N. p., 1985. Web.
Spurlin, Stanford R, & Yeung, Edward S. Sulfide chemiluminescence detection. United States.
Spurlin, Stanford R, and Yeung, Edward S. Tue . "Sulfide chemiluminescence detection". United States. https://www.osti.gov/servlets/purl/865685.
@article{osti_865685,
title = {Sulfide chemiluminescence detection},
author = {Spurlin, Stanford R and Yeung, Edward S},
abstractNote = {A method of chemiluminescently determining a sulfide which is either hydrogen sulfide or methyl mercaptan by reacting the sulfide with chlorine dioxide at low pressure and under conditions which allow a longer reaction time in emission of a single photon for every two sulfide containing species, and thereafter, chemiluminescently detecting and determining the sulfide. The invention also relates not only to the detection method, but the novel chemical reaction and a specifically designed chemiluminescence detection cell for the reaction.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1985},
month = {1}
}