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Title: Catalyst for the methanation of carbon monoxide in sour gas

Abstract

The invention involves the synergistic effect of the specific catalytic constituents on a specific series of carriers for the methanation of carbon monoxide in the presence of sulfur at relatively high temperatures and at low steam to gas ratios in the range of 0.2:1 or less. This effect was obtained with catalysts comprising the mixed sulfides and oxides of nickel and chromium supported on carriers comprising magnesium aluminate and magnesium silicate. Conversion of carbon monoxide to methane was in the range of from 40 to 80%. Tests of this combination of metal oxides and sulfides on other carriers and tests of other metal oxides and sulfides on the same carrier produced a much lower level of conversion.

Inventors:
 [1];  [1]
  1. Louisville, KY
Issue Date:
OSTI Identifier:
865591
Patent Number(s):
4540681
Assignee:
United Catalysts, Inc. (Louisville, KY)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
DOE Contract Number:  
EX-76-6-01-20232
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
catalyst; methanation; carbon; monoxide; sour; gas; involves; synergistic; effect; specific; catalytic; constituents; series; carriers; presence; sulfur; relatively; temperatures; steam; ratios; range; obtained; catalysts; comprising; mixed; sulfides; oxides; nickel; chromium; supported; magnesium; aluminate; silicate; conversion; methane; 40; 80; tests; combination; metal; carrier; produced; level; carbon monoxide; metal oxide; metal oxides; synergistic effect; catalysts comprising; /502/48/518/

Citation Formats

Kustes, William A, and Hausberger, Arthur L. Catalyst for the methanation of carbon monoxide in sour gas. United States: N. p., 1985. Web.
Kustes, William A, & Hausberger, Arthur L. Catalyst for the methanation of carbon monoxide in sour gas. United States.
Kustes, William A, and Hausberger, Arthur L. Tue . "Catalyst for the methanation of carbon monoxide in sour gas". United States. https://www.osti.gov/servlets/purl/865591.
@article{osti_865591,
title = {Catalyst for the methanation of carbon monoxide in sour gas},
author = {Kustes, William A and Hausberger, Arthur L},
abstractNote = {The invention involves the synergistic effect of the specific catalytic constituents on a specific series of carriers for the methanation of carbon monoxide in the presence of sulfur at relatively high temperatures and at low steam to gas ratios in the range of 0.2:1 or less. This effect was obtained with catalysts comprising the mixed sulfides and oxides of nickel and chromium supported on carriers comprising magnesium aluminate and magnesium silicate. Conversion of carbon monoxide to methane was in the range of from 40 to 80%. Tests of this combination of metal oxides and sulfides on other carriers and tests of other metal oxides and sulfides on the same carrier produced a much lower level of conversion.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 01 00:00:00 EST 1985},
month = {Tue Jan 01 00:00:00 EST 1985}
}