High surface area ThO.sub.2 catalyst and method of preparing it
Abstract
A ThO.sub.2 catalyst having a high surface area of about 80-125 m.sup.2 /g is synthesized. The compound is synthesized by simultaneously mixing an aqueous solution of ThNO.sub.3 (NO.sub.3).sub.4.4H.sub.2 O with an aqueous solution of Na.sub.2 CO.sub.3.H.sub.2 O, to produce a solution and solid ThOCO.sub.3. The solid ThOCO.sub.3 is separated from the solution, and then calcined at a temperature of about 225.degree.-300.degree. C. for about 40-55 hours to produce ThO.sub.2. The ThO.sub.2 catalyst produced includes Na present as a substitutional cation in an amount equal to about 5-10 atom percent.
- Inventors:
-
- Alamo, CA
- Berkeley, CA
- Walnut Creek, CA
- Issue Date:
- Research Org.:
- Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
- OSTI Identifier:
- 865536
- Patent Number(s):
- 4532230
- Assignee:
- United States of America as represented by United States (Washington, DC)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
- DOE Contract Number:
- W-7405-ENG-48
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- surface; catalyst; method; preparing; 80-125; synthesized; compound; simultaneously; mixing; aqueous; solution; thno; 4h; na; produce; solid; thoco; separated; calcined; temperature; 225; degree; -300; 40-55; hours; produced; substitutional; cation; amount; equal; 5-10; atom; percent; amount equal; atom percent; aqueous solution; simultaneously mix; /502/423/
Citation Formats
Colmenares, Carlos A, Somorjai, Gabor A, and Maj, Joseph J. High surface area ThO.sub.2 catalyst and method of preparing it. United States: N. p., 1985.
Web.
Colmenares, Carlos A, Somorjai, Gabor A, & Maj, Joseph J. High surface area ThO.sub.2 catalyst and method of preparing it. United States.
Colmenares, Carlos A, Somorjai, Gabor A, and Maj, Joseph J. Tue .
"High surface area ThO.sub.2 catalyst and method of preparing it". United States. https://www.osti.gov/servlets/purl/865536.
@article{osti_865536,
title = {High surface area ThO.sub.2 catalyst and method of preparing it},
author = {Colmenares, Carlos A and Somorjai, Gabor A and Maj, Joseph J},
abstractNote = {A ThO.sub.2 catalyst having a high surface area of about 80-125 m.sup.2 /g is synthesized. The compound is synthesized by simultaneously mixing an aqueous solution of ThNO.sub.3 (NO.sub.3).sub.4.4H.sub.2 O with an aqueous solution of Na.sub.2 CO.sub.3.H.sub.2 O, to produce a solution and solid ThOCO.sub.3. The solid ThOCO.sub.3 is separated from the solution, and then calcined at a temperature of about 225.degree.-300.degree. C. for about 40-55 hours to produce ThO.sub.2. The ThO.sub.2 catalyst produced includes Na present as a substitutional cation in an amount equal to about 5-10 atom percent.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1985},
month = {1}
}
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