Super ionic conductive glass
Abstract
An ionically conducting glass for use as a solid electrolyte in a power or secondary cell containing an alkali metal-containing anode and a cathode separated by an alkali metal ion conducting glass having an ionic transference number of unity and the general formula: A.sub.1+x D.sub.2-x/3 Si.sub.x P.sub.3-x O.sub.12-2x/3, wherein A is a network modifier for the glass and is an alkali metal of the anode, D is an intermediate for the glass and is selected from the class consisting of Zr, Ti, Ge, Al, Sb, Be, and Zn and X is in the range of from 2.25 to 3.0. Of the alkali metals, Na and Li are preferred and of the intermediate, Zr, Ti and Ge are preferred.
- Inventors:
-
- Park Forest, IL
- Fort Collins, CO
- Issue Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- OSTI Identifier:
- 865131
- Patent Number(s):
- 4465744
- Assignee:
- United States of America as represented by United States (Washington, DC)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C03 - GLASS C03C - CHEMICAL COMPOSITION OF GLASSES, GLAZES, OR VITREOUS ENAMELS
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- DOE Contract Number:
- W-31109-ENG-38
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- super; ionic; conductive; glass; ionically; conducting; solid; electrolyte; power; secondary; cell; containing; alkali; metal-containing; anode; cathode; separated; metal; transference; unity; formula; 2-x; 3-x; 12-2x; network; modifier; intermediate; selected; consisting; zr; sb; zn; range; 25; metals; na; preferred; conductive glass; alkali metal-containing; alkali metal; solid electrolyte; alkali metals; cell containing; secondary cell; cathode separated; ionically conducting; cell contain; conducting glass; /429/501/
Citation Formats
Susman, Sherman, and Volin, Kenneth J. Super ionic conductive glass. United States: N. p., 1984.
Web.
Susman, Sherman, & Volin, Kenneth J. Super ionic conductive glass. United States.
Susman, Sherman, and Volin, Kenneth J. Sun .
"Super ionic conductive glass". United States. https://www.osti.gov/servlets/purl/865131.
@article{osti_865131,
title = {Super ionic conductive glass},
author = {Susman, Sherman and Volin, Kenneth J},
abstractNote = {An ionically conducting glass for use as a solid electrolyte in a power or secondary cell containing an alkali metal-containing anode and a cathode separated by an alkali metal ion conducting glass having an ionic transference number of unity and the general formula: A.sub.1+x D.sub.2-x/3 Si.sub.x P.sub.3-x O.sub.12-2x/3, wherein A is a network modifier for the glass and is an alkali metal of the anode, D is an intermediate for the glass and is selected from the class consisting of Zr, Ti, Ge, Al, Sb, Be, and Zn and X is in the range of from 2.25 to 3.0. Of the alkali metals, Na and Li are preferred and of the intermediate, Zr, Ti and Ge are preferred.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sun Jan 01 00:00:00 EST 1984},
month = {Sun Jan 01 00:00:00 EST 1984}
}
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