Glass capable of ionic conduction and method of preparation
Abstract
Sulfide glasses capable of conducting alkali metal ions are prepared from a nonmetal glass former such as GeS.sub.2, B.sub.2 S.sub.3 and SiS.sub.2 in mixture with a glass modifier such as Na.sub.2 S or another alkali metal sulfide. A molten mixture of the constituents is rapidly quenched to below the glass transition temperature by contact with a metal mold. The rapid quench is sufficient to prevent crystallization and permit solidification as an amorphous solid mixture. An oxygen-free atmosphere is maintained over the mixture to prevent oxidation. A new glass system of (1-X) Na.sub.2 O:XB.sub.2 S.sub.3 is disclosed.
- Inventors:
-
- Park Forest, IL
- Downers Grove, IL
- Fort Collins, CO
- Jerusalem, IL
- Issue Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- OSTI Identifier:
- 864896
- Patent Number(s):
- 4432891
- Assignee:
- United States of America as represented by United States (Washington, DC)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C03 - GLASS C03C - CHEMICAL COMPOSITION OF GLASSES, GLAZES, OR VITREOUS ENAMELS
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- DOE Contract Number:
- W-31109-ENG-38
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- glass; capable; ionic; conduction; method; preparation; sulfide; glasses; conducting; alkali; metal; prepared; nonmetal; former; sis; mixture; modifier; na; molten; constituents; rapidly; quenched; below; transition; temperature; contact; mold; rapid; quench; sufficient; prevent; crystallization; permit; solidification; amorphous; solid; oxygen-free; atmosphere; maintained; oxidation; 1-x; xb; disclosed; rapidly quenched; glass former; metal sulfide; alkali metal; transition temperature; solid mixture; glass transition; oxygen-free atmosphere; molten mixture; prevent oxidation; prevent crystallization; rapid quench; nonmetal glass; ionic conduction; sulfide glasses; glass modifier; glasses capable; glass capable; free atmosphere; metal glass; amorphous solid; conducting alkali; /252/429/501/
Citation Formats
Susman, Sherman, Delbecq, Charles J, Volin, Kenneth J, and Boehm, Leah. Glass capable of ionic conduction and method of preparation. United States: N. p., 1984.
Web.
Susman, Sherman, Delbecq, Charles J, Volin, Kenneth J, & Boehm, Leah. Glass capable of ionic conduction and method of preparation. United States.
Susman, Sherman, Delbecq, Charles J, Volin, Kenneth J, and Boehm, Leah. Sun .
"Glass capable of ionic conduction and method of preparation". United States. https://www.osti.gov/servlets/purl/864896.
@article{osti_864896,
title = {Glass capable of ionic conduction and method of preparation},
author = {Susman, Sherman and Delbecq, Charles J and Volin, Kenneth J and Boehm, Leah},
abstractNote = {Sulfide glasses capable of conducting alkali metal ions are prepared from a nonmetal glass former such as GeS.sub.2, B.sub.2 S.sub.3 and SiS.sub.2 in mixture with a glass modifier such as Na.sub.2 S or another alkali metal sulfide. A molten mixture of the constituents is rapidly quenched to below the glass transition temperature by contact with a metal mold. The rapid quench is sufficient to prevent crystallization and permit solidification as an amorphous solid mixture. An oxygen-free atmosphere is maintained over the mixture to prevent oxidation. A new glass system of (1-X) Na.sub.2 O:XB.sub.2 S.sub.3 is disclosed.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1984},
month = {1}
}
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